快速电子轰击甲醇冰的实验模拟及其对天体化学的影响

Fabricio Moreira Freitas, S. Pilling
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摘要

在这项工作中,我们通过实验模拟了甲醇(CH3OH)在快速电子(4.9 keV)轰击下的结冰行为(12 K),试图模拟太空环境中辐射诱发的辐射化学反应。样品红外光谱分析显示,在样品轰击过程中出现了新的物种,包括 CO2、CO、H2O 和 CH4。我们对甲醇的有效破坏截面(5.5 × 10-19 cm2)进行了量化,并确定了这些新产生物质的形成截面。此外,我们还描述了化学平衡(CE)阶段的特征,该阶段在较高的通量下变得明显。我们还计算了分子丰度,并评估了同一样品中快速电子诱导的解吸产率。此外,我们还估算了在受电子影响的特定天体物理环境中实现化学平衡所需的时间尺度。这项研究大大有助于我们理解天体物理冰的电子轰击行为,并能与太空环境中富含有机物的冰进行有意义的比较。
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EXPERIMENTAL SIMULATION OF FAST ELECTRON BOMBARDMENT OF METHANOL ICE AND ITS IMPLICATIONS IN ASTROCHEMISTRY
In this work, we experimentally simulate the methanol (CH3OH) ice behavior (12 K) through the bombarded by fast electrons (4.9 keV) in an attempt to simulate radiation chemistry induced by radiation in space environments. The sample analysis by infrared spectroscopy reveals the appearance of new species, including CO2, CO, H2O, and CH4, during the sample bombardment. We have quantified the effective destruction cross-section of methanol (5.5 × 10-19 cm2) and determined the formation cross-section for these newly produced species. Additionally, we have characterized the chemical equilibrium (CE) phase, which becomes evident at higher fluences. We have also calculated molecular abundances and assessed the desorption yield induced by fast electrons within the same sample. Furthermore, we estimated the timescale required to achieve chemical equilibrium in specific astrophysical environments impacted by electrons. This study significantly contributes to our comprehension of electron bombardment behavior in astrophysical ices and allows for meaningful comparisons with organic-rich ices in space environments
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