使用含铁金属促进剂的 Ni/Al2O3 催化剂从二氧化碳 (CO2) 气体中生成甲烷气体

Tiara Manda Putri, Robert Junaidi, Anerasari Meidinariasty
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摘要

二氧化碳(CO2)是造成温室效应的最重要原因之一。一种可以减少全球变暖问题的方法是将二氧化碳转化为甲烷,并利用二氧化碳加氢反应将其转化为甲烷。本研究旨在利用固定床反应器进行二氧化碳甲烷化过程,从二氧化碳气体中获取甲烷气体。本研究以 Ni/Al2O3 催化剂为载体,以金属铁为促进剂,采用原位法,改变金属铁促进剂的用量至 1 克至 5 克,时间变化为 30 分钟、45 分钟和 60 分钟。在样品 15 中,金属铁促进剂的用量为 5 克(变化量为 1-5 克),时间为 60 分钟(变化量为 30 分钟、45 分钟和 60 分钟),甲烷产气量最高,达到 12.54%。金属铁促进剂的用量和使用时间的长短与产生的甲烷气体(CH4)成正比。这是因为添加 Fe 作为促进剂可以提高催化剂的活性和催化剂的稳定性,从而使催化剂在将 CO2 转化为甲烷热气时能很好地发挥作用:二氧化碳 CO2 甲烷化 催化剂 Ni/Al2O3 促进剂 Fe 甲烷 (CH4)
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Pembuatan Gas Metana Dari Gas Karbon Dioksida (CO2) Menggunakan Katalis Ni/Al2O3 Dengan Promotor Logam Fe
Carbon dioxide (CO2) is one of the most critical greenhouse effect causes. One method that can reduce the problem of global warming is by converting CO2 and utilizing it into a CO2 hydrogenation reaction into methane. This research aims to obtain methane gas from CO2 gas using a Fixed Bed Reactor for the CO2 methanation process. This research uses Ni/Al2O3 catalyst as support and Fe metal as a promoter with in situ method by varying the amount of Fe metal promoter up to 1gr - 5gr and time variation of 30 minutes, 45 minutes and 60 minutes. The highest methane gas yield was obtained in sample 15 with more Fe metal promoter 5 gr (variation 1-5 gr) for 60 minutes (variation 30, 45, and 60 minutes), which amounted to 12.54%. The amount of Fe metal promoter and the length of time used is directly proportional to the methane gas (CH4) produced. This is because the addition of Fe as a promoter can increase catalyst activity and catalyst stability, so that the catalyst can work well in converting CO2 into methane thermal gas.Keywords: Carbon Dioxide, CO2 Methanation, Catalyst Ni/Al2O3, Promoter Fe, Methane (CH4).
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