使用添加锰作为促进剂的 Ni/Al2O3 催化剂从二氧化碳中生成甲烷气体

Jihan Syahira Syifa Friema, Robert Junaidi, Mustain Zamhari
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摘要

二氧化碳(CO2)排放是温室气体排放的一种,是造成全球变暖现象的主要因素。从二氧化碳的排放总量来看,有三个部分对二氧化碳的高排放量影响最大,即电力部门(42%)、交通部门(23%)和住房部门(6%)。如果不在全球范围内采取预防措施,二氧化碳增加的趋势将持续下去。预防措施之一是将二氧化碳(CO2)转化为甲烷(CH4),或称为二氧化碳的甲烷化过程。在燃料领域,将二氧化碳转化为甲烷气体在热力学方面更具优势。决定甲烷化过程的因素之一是催化剂的活性。本研究使用的催化剂是 Ni/Al2O3 催化剂。Ni/Al2O3 催化剂是一种在甲烷形成过程中性能良好的催化剂。然而,Ni/Al2O3 催化剂也有缺点,其中之一就是催化剂上容易出现碳沉积和烧结。提高催化剂稳定性能的方法之一是添加促进剂。本研究通过改变温度、Ni/Al2O3 催化剂的用量和添加促进剂来改变催化剂的结构。结果表明,温度和催化剂用量会影响 CH4 的生成量,而添加锰(Mn)引发剂会影响催化剂的孔结构。
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Pembentukan Gas Metan dari Karbon Dioksida Menggunakan Katalis Ni/Al2O3 dengan Penambahan Mn Sebagai Promotor
Carbon dioxide (CO2) emissions are a type of greenhouse gas emission which is the main factor in the emergence of the global warming phenomenon. Based on the total CO2 emissions released, there are 3 components that most influence high CO2 emissions, namely the electricity sector (42%), transportation (23%) and housing (6%). The trend of increasing CO2 will continue if no preventive measures are taken globally. One of these preventive efforts is to convert carbon dioxide (CO2) into methane (CH4), or known as the methanation process of carbon dioxide. In the field of fuel, the conversion of carbon dioxide into methane gas has more advantages in terms of thermodynamics. One of the factors that determine the methanation process is the activity of the catalyst. The catalyst used in this study was the Ni/Al2O3 catalyst. Ni/Al2O3 catalyst is a catalyst that has good performance in the methane formation process. However, the Ni/Al2O3 catalyst has disadvantages, one of which is that it is susceptible to carbon deposition and sintering on the catalyst. One way to improve catalyst stability performance is by adding a promoter. This research was carried out by varying the temperature, the amount of Ni/Al2O3 catalyst and adding a promoter to give structural changes to the catalyst. The results showed that the temperature and the amount of catalyst affect the amount of CH4 formed, and the addition of manganese (Mn) initiator can affect the pore structure of the catalyst.
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