甘蔗甜菜碱作为生物柴油生产过程的催化剂

Raysha Amelya, Indah Purnamasari, Muhammad Yerizam
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摘要

甘蔗是一种植物,因其含糖量高而被加工成冰糖。制糖过程中会产生废物,其中之一就是糖蜜废物。本研究旨在利用碳化法和磺化法将糖蜜转化为催化剂。磺化法采用 2、4、6、8 和 10 N H2SO4 溶液浓度的变化以及 2、4 和 6 小时磺化时间的变化,以获得最佳的糖蜜催化剂。催化剂表征包括通过酸碱滴定、傅立叶变换红外光谱和扫描电镜-电子显微镜观察表面酸度。本研究还旨在使用最佳糖蜜催化剂生产生物柴油。表面酸度分析结果表明,在 10 N H2SO4 浓度和 6 小时 0.907 mmol/gr 的条件下,糖蜜催化剂的表面酸度最佳。FT-IR 测试结果表明,在波数 1149.74 cm-1 和 1038.57 cm-1 处存在 O=S=O 官能团。SEM 和 EDX 分析结果表明,磺化后的糖蜜催化剂孔隙更小,碳片上的硫基更多。使用糖蜜催化剂生产的生物柴油收率为 84.51%。
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Tetes Tebu Menjadi Katalis Untuk Proses Pembuatan Biodiesel
Sugar cane is a plant that is processed into crystal sugar because it contains high sugar content. Sugar production produces waste, one of which is molasses waste. This study aims to obtain molasses into a catalyst using the carbonization method and the sulfonation method. The sulfonation method uses variations in the concentration of 2, 4, 6, 8, and 10 N H2SO4 solution and variations in sulfonation time of 2, 4, and 6 hours to get the best molasses catalyst. Catalyst characterization includes surface acidity by acid-base titration, FT-IR, and SEM-EDX. This research also aims to produce biodiesel yield using the best molasses catalyst. The results of surface acidity analysis showed that the best molasses catalyst was obtained at 10 N H2SO4 concentration with 6 hours at 0.907 mmol/gr. FT-IR test results showed the presence of O=S=O functional groups at wave numbers 1149.74 cm-1 and 1038.57 cm-1. SEM and EDX analysis results showed that the molasses catalyst after sulfonation had smaller pores and more sulfur groups on the carbon sheet. The yield of biodiesel produced using a molasses catalyst was 84.51%.
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