碱化对三叶草纤维生物复合材料机械性能的影响

E. Widodo, Ali Akbar, Boy Isma Putra
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摘要

碱处理天然纤维的作用是去除半纤维素和木质素层。半纤维素和木质素层阻止基质与天然纤维纤维素结构结合。使用不适当的碱会降低其效果,甚至会损坏纤维素层。本研究比较了碱性 NaOH、CaOH 和 KOH 去除木质素和半纤维素的效果,以及它们保持纤维素含量的能力。在碱性溶液中使用浸泡法可以得到很好的控制。傅立叶变换红外特性测试用于检测官能团的变化,TGV 测试用于检测耐热能力,XRD 测试用于检测三叶草天然纤维结晶和无定形特性的结构变化。此外,还进行了拉伸试验,以确定碱性处理对机械强度拉伸强度变化的影响。测试结果表明,碱性 NaOH 通过检测纤维素的存在、拉伸强度和结晶原子结构的性质,给出了最佳特性。 亮点: 碱类型的有效性:比较 NaOH、CaOH 和 KOH 在去除木质素和半纤维素的同时保留纤维素含量的效果。 表征技术:傅立叶变换红外光谱(FTIR)、热重分析(TGA)和 XRD 测试用于评估官能团变化、耐热性和结构特性。 NaOH 优越性:碱性 NaOH 处理在保持纤维素、提高拉伸强度和影响原子结构方面效果最佳。 关键词碱处理 天然纤维 去除木质素 保存纤维素 抗张强度
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The Effect of Alkalization on the Mechanical Properties of Sansevieria Fiber Bio-Composit
Alkali treatment of natural fibers has a role in removing hemicellulose and lignin layers. This layer prevents the matrix from bonding with the natural fiber cellulose structure. The use of an inappropriate type of alkali will reduce its effectiveness and can even damage the cellulose layer. This study compared the effectiveness of alkaline NaOH, CaOH and KOH in removing lignin and hemicellulose and their ability to maintain cellulose content. The use of the immersion method in alkaline solutions is well controlled. The FTIR characterization test was used to detect functional group changes, the TGV test to detect heat resistance ability, the XRD test to detect structural changes in crystalline and amorphous properties of sansevieria natural fibers. Furthermore, the tensile test to determine the effect of alkaline treatment on changes in mechanical strength Tensile strength. From the test results it was found that the alkaline NaOH gave the best characteristics by detecting the presence of cellulose, tensile strength and the nature of the crystalline atomic structure. Highlights:  Effectiveness of Alkali Types: Comparison of NaOH, CaOH, and KOH effectiveness in removing lignin and hemicellulose while preserving cellulose content. Characterization Techniques: FTIR, TGA, and XRD tests used for functional group changes, heat resistance, and structural properties evaluation. NaOH Superiority: Alkaline NaOH treatment demonstrated best results in maintaining cellulose, enhancing tensile strength, and influencing atomic structure. Keywords: Alkali treatment, Natural fibers, Lignin removal, Cellulose preservation, Tensile strength.
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