用烷基聚糖苷-十二醇配方提高吸油效率

Lorenzo Veronico, Giuseppe Colafemmina, Luigi Gentile
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摘要

这项研究为生物表面活性剂系统提供了宝贵的见解,揭示了它们在清洁和采油过程中的行为和潜在应用。通过将烷基多糖苷 Triton® CG-110 与 C12OH 脂肪醇相结合,一种很有前景的策略应运而生,它提高了基于表面活性剂的配方的效率。这种创新方法为各种工业应用中的可持续解决方案铺平了道路。对含有 C12OH 的配方进行的流变学分析表明,在 Triton 含量不超过 3.2 v/v% 的情况下,配方具有类似牛顿的行为,而在 Triton 含量为 6.4 v/v% 的体系中则出现了粘弹性反应。自扩散核磁共振显示,C12OH 形成了较大的聚集体,不同于传统的球形胶束溶液。此外,清洁效率测试表明,C12OH 显著提高了表面活性剂体系的吸油能力。这项研究确定了含有 C12OH 的样品中与南联 III 微乳相相对应的最佳配方点。这一关键发现展示了定制表面活性剂混合物的潜力,为实现更环保、更有效的工业实践指明了道路。
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Enhancing Oil-Uptake Efficiency with an Alkyl Polyglycoside–Dodecanol Formulation
This study provides valuable insights into biosurfactant systems, shedding light on their behavior and potential applications in cleaning and oil recovery processes. By combining the alkyl polyglycoside Triton® CG-110 with C12OH fatty alcohol, a promising strategy emerges, enhancing the efficiency of surfactant-based formulations. This innovative approach paves the way for sustainable solutions in diverse industrial applications. A rheological analysis of the formulations containing C12OH demonstrated a Newtonian-like behavior of up to 3.2 v/v% of Triton, while a viscoelastic response was observed in a system containing 6.4 v/v% of Triton. Self-diffusion nuclear magnetic resonance revealed the formation of larger aggregates with C12OH, diverging from the classical spherical micellar solution. Moreover, cleaning efficiency tests highlighted C12OH’s significant enhancement of the surfactant system’s oil-uptake capacity. This study identified the optimum formulation point, corresponding to the Winsor III microemulsion phase, in samples containing C12OH. This pivotal discovery showcases the potential of tailored surfactant blends, indicating a path toward greener and more effective industrial practices.
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