熔融含钛高炉渣自发结晶过程中的残余应力分析与机理研究

Crystals Pub Date : 2024-01-10 DOI:10.3390/cryst14010070
Daizheng Wang, Bing-jun Yan, Ziyu Dang, Peng Li, Hongwei Guo, Ziyu Song
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摘要

通过控制合理的热处理系统,可利用熔融含钛高炉矿渣获得铸石材料。在这一过程中获得的材料会产生残余应力,从而影响材料的宏观特性。本文基于含钛产品的自结晶能力,模拟了微晶铸石的制造过程。该研究利用 X 射线衍射法精确、方便地评估了微晶铸石的残余应力,并研究了粘度和热膨胀系数如何影响残余应力水平。该研究为解释含钛高炉矿渣提供了理论基础,并结合 XRD(X 射线衍射)、SEM(扫描电子显微镜)、DTA(差热分析)等表征方法以及 Factpage 和 Fullprop 等理论计算,研究了 TiO2 含量通过残余应力对微晶铸石自结晶机械特性的微观结构的影响。实验结果表明,随着体系中 TiO2 含量的增加,玻璃相减少,结晶度提高,主晶相由长石相变为透辉石相。此外,其粘度、热膨胀系数和残余应力均有所降低,而相应的抗压强度和抗弯强度则有所提高。
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Analysis and Mechanism Study of Residual Stress during the Spontaneous Crystallisation Process of Molten Titanium-Containing Blast Furnace Slag
Molten titanium-containing blast furnace slag can be used to obtain cast stone materials by controlling a reasonable heat treatment system. The material acquired during this process showcases residual stress, which additionally impacts the macroscopic characteristics of the material. This article simulates the process of manufacturing microcrystalline cast stones based on the self-crystallisation ability of titanium-containing products. This research employs X-ray diffraction to precisely and conveniently assess the residual stress of microcrystalline cast stones and investigates how viscosity and the thermal expansion coefficient influence the residual stress level. The study provides a theoretical foundation for explaining titanium-containing blast furnace slag and combines characterisation methods such as XRD (X-ray diffraction), SEM (Scanning electron microscope), DTA (Differential thermal analysis), and theoretical calculations such as Factpage and Fullprop to study the effect of the TiO2 content on the microstructure of self-crystallised mechanical characteristics of microcrystalline cast stones through residual stress. The results of the experiment indicate that as the TiO2 content in the system increases, the glass phase is reduced, the crystallinity improves, and the main crystal phase changes from a feldspar phase to a diopside phase. Furthermore, its viscosity, thermal expansion coefficient, and residual stress decrease while its corresponding compressive strength and bending strength increase.
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