A. A. Ulyankina, A. D. Tsarenko, T. A. Molodtsova, M. V. Gorshenkov, N. V. Smirnova
{"title":"用于光电化学应用的 ZnO/ZnWO4 纳米复合材料的合成及其特性","authors":"A. A. Ulyankina, A. D. Tsarenko, T. A. Molodtsova, M. V. Gorshenkov, N. V. Smirnova","doi":"10.1134/s1023193523120145","DOIUrl":null,"url":null,"abstract":"<h3 data-test=\"abstract-sub-heading\">Abstract</h3><p>A series of ZnO/ZnWO<sub>4</sub> nanocomposites with different ZnWO<sub>4</sub> content, are electrochemically synthesized under pulse alternating current starting from ZnO and WO<sub>3</sub> nanopowders. A complex of physicochemical methods (X-ray diffraction analysis, Raman spectroscopy, transmission electron microscopy, energy dispersive X-ray microanalysis) was used to study the composition and structural characteristics of the obtained materials. The nanocomposite with optimal composition (ZnWO<sub>4</sub> ~6%) was used as a photoanode material for a flow photocatalytic fuel cell with sulfate electrolyte added with organic and inorganic fuel. The maximum values of <i>E</i><sub>oc</sub> (850 mV) and <i>P</i><sub>max</sub> (85.8 μW/cm<sup>2</sup>) are achieved using Na<sub>2</sub>SO<sub>4</sub> with the addition of glucose as a fuel.</p>","PeriodicalId":760,"journal":{"name":"Russian Journal of Electrochemistry","volume":"1 1","pages":""},"PeriodicalIF":1.1000,"publicationDate":"2024-01-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Synthesis and Properties of ZnO/ZnWO4-Nanocomposites for Photoelectrochemical Applications\",\"authors\":\"A. A. Ulyankina, A. D. Tsarenko, T. A. Molodtsova, M. V. Gorshenkov, N. V. Smirnova\",\"doi\":\"10.1134/s1023193523120145\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<h3 data-test=\\\"abstract-sub-heading\\\">Abstract</h3><p>A series of ZnO/ZnWO<sub>4</sub> nanocomposites with different ZnWO<sub>4</sub> content, are electrochemically synthesized under pulse alternating current starting from ZnO and WO<sub>3</sub> nanopowders. A complex of physicochemical methods (X-ray diffraction analysis, Raman spectroscopy, transmission electron microscopy, energy dispersive X-ray microanalysis) was used to study the composition and structural characteristics of the obtained materials. The nanocomposite with optimal composition (ZnWO<sub>4</sub> ~6%) was used as a photoanode material for a flow photocatalytic fuel cell with sulfate electrolyte added with organic and inorganic fuel. The maximum values of <i>E</i><sub>oc</sub> (850 mV) and <i>P</i><sub>max</sub> (85.8 μW/cm<sup>2</sup>) are achieved using Na<sub>2</sub>SO<sub>4</sub> with the addition of glucose as a fuel.</p>\",\"PeriodicalId\":760,\"journal\":{\"name\":\"Russian Journal of Electrochemistry\",\"volume\":\"1 1\",\"pages\":\"\"},\"PeriodicalIF\":1.1000,\"publicationDate\":\"2024-01-16\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Russian Journal of Electrochemistry\",\"FirstCategoryId\":\"5\",\"ListUrlMain\":\"https://doi.org/10.1134/s1023193523120145\",\"RegionNum\":4,\"RegionCategory\":\"工程技术\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"ELECTROCHEMISTRY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Russian Journal of Electrochemistry","FirstCategoryId":"5","ListUrlMain":"https://doi.org/10.1134/s1023193523120145","RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"ELECTROCHEMISTRY","Score":null,"Total":0}
Synthesis and Properties of ZnO/ZnWO4-Nanocomposites for Photoelectrochemical Applications
Abstract
A series of ZnO/ZnWO4 nanocomposites with different ZnWO4 content, are electrochemically synthesized under pulse alternating current starting from ZnO and WO3 nanopowders. A complex of physicochemical methods (X-ray diffraction analysis, Raman spectroscopy, transmission electron microscopy, energy dispersive X-ray microanalysis) was used to study the composition and structural characteristics of the obtained materials. The nanocomposite with optimal composition (ZnWO4 ~6%) was used as a photoanode material for a flow photocatalytic fuel cell with sulfate electrolyte added with organic and inorganic fuel. The maximum values of Eoc (850 mV) and Pmax (85.8 μW/cm2) are achieved using Na2SO4 with the addition of glucose as a fuel.
期刊介绍：
Russian Journal of Electrochemistry is a journal that covers all aspects of research in modern electrochemistry. The journal welcomes submissions in English or Russian regardless of country and nationality of authors.
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