Elvira Tarasova, Nutan Savale, Peeter-Mihkel Ausmaa, Illia Krasnou, Andres Krumme
{"title":"纤维素在与绿色助溶剂混合的新型[mTBNH][OAc]离子液体中的流变性和溶解能力","authors":"Elvira Tarasova, Nutan Savale, Peeter-Mihkel Ausmaa, Illia Krasnou, Andres Krumme","doi":"10.1007/s00397-024-01433-3","DOIUrl":null,"url":null,"abstract":"<div><p>Dissolution of cellulose is crucial for its regeneration and chemical modification, such as homogeneous transesterification, for example. The cellulose dissolution in ionic liquid (IL) media is suggested as a prospective environmentally friendly alternative to conventional solvents. In this study, novel distillable ionic liquid 5-methyl-1,5,7-triaza-bicyclo-[4.3.0]non-6-enium acetate, [mTBNH][OAc] was used for cellulose dissolution. This IL has high dissolving power towards cellulose and durability for recycling. However, the disadvantage of ILs is their high viscosity, which limits the supreme cellulose concentration in IL solutions, and their high cost, hindering their commercialization. The addition of low-viscous, low-cost, and naturally derived co-solvents can reduce the overall viscosity and cost. In this study, rheology experiments were conducted to investigate the flow behavior of cellulose in [mTBNH][OAc] ionic liquid mixed with the green co-solvents such as γ-Valerolactone (GVL), dimethyl isosorbide (DMI), and N,N′-dimethylpropyleneurea (DMPU). A study of the rheology showed that the viscosity reduces at low doses of co-solvent (≤ 50 wt%) but causes the structuring of the cellulose solution and its gelation (or phase separation) at high doses (≥ 50 wt%). The rheological study also indicated that the flow activation energy of cellulose in IL/co-solvent systems is lower than that in pure IL and decays in the order of DMPU > DMI > GVL > DMSO.</p><h3>Graphical abstract</h3>\n<div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":755,"journal":{"name":"Rheologica Acta","volume":"63 2","pages":"167 - 178"},"PeriodicalIF":2.3000,"publicationDate":"2024-01-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Rheology and dissolution capacity of cellulose in novel [mTBNH][OAc] ionic liquid mixed with green co-solvents\",\"authors\":\"Elvira Tarasova, Nutan Savale, Peeter-Mihkel Ausmaa, Illia Krasnou, Andres Krumme\",\"doi\":\"10.1007/s00397-024-01433-3\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>Dissolution of cellulose is crucial for its regeneration and chemical modification, such as homogeneous transesterification, for example. The cellulose dissolution in ionic liquid (IL) media is suggested as a prospective environmentally friendly alternative to conventional solvents. In this study, novel distillable ionic liquid 5-methyl-1,5,7-triaza-bicyclo-[4.3.0]non-6-enium acetate, [mTBNH][OAc] was used for cellulose dissolution. This IL has high dissolving power towards cellulose and durability for recycling. However, the disadvantage of ILs is their high viscosity, which limits the supreme cellulose concentration in IL solutions, and their high cost, hindering their commercialization. The addition of low-viscous, low-cost, and naturally derived co-solvents can reduce the overall viscosity and cost. In this study, rheology experiments were conducted to investigate the flow behavior of cellulose in [mTBNH][OAc] ionic liquid mixed with the green co-solvents such as γ-Valerolactone (GVL), dimethyl isosorbide (DMI), and N,N′-dimethylpropyleneurea (DMPU). A study of the rheology showed that the viscosity reduces at low doses of co-solvent (≤ 50 wt%) but causes the structuring of the cellulose solution and its gelation (or phase separation) at high doses (≥ 50 wt%). The rheological study also indicated that the flow activation energy of cellulose in IL/co-solvent systems is lower than that in pure IL and decays in the order of DMPU > DMI > GVL > DMSO.</p><h3>Graphical abstract</h3>\\n<div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>\",\"PeriodicalId\":755,\"journal\":{\"name\":\"Rheologica Acta\",\"volume\":\"63 2\",\"pages\":\"167 - 178\"},\"PeriodicalIF\":2.3000,\"publicationDate\":\"2024-01-18\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Rheologica Acta\",\"FirstCategoryId\":\"5\",\"ListUrlMain\":\"https://link.springer.com/article/10.1007/s00397-024-01433-3\",\"RegionNum\":3,\"RegionCategory\":\"工程技术\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"MECHANICS\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Rheologica Acta","FirstCategoryId":"5","ListUrlMain":"https://link.springer.com/article/10.1007/s00397-024-01433-3","RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"MECHANICS","Score":null,"Total":0}
Rheology and dissolution capacity of cellulose in novel [mTBNH][OAc] ionic liquid mixed with green co-solvents
Dissolution of cellulose is crucial for its regeneration and chemical modification, such as homogeneous transesterification, for example. The cellulose dissolution in ionic liquid (IL) media is suggested as a prospective environmentally friendly alternative to conventional solvents. In this study, novel distillable ionic liquid 5-methyl-1,5,7-triaza-bicyclo-[4.3.0]non-6-enium acetate, [mTBNH][OAc] was used for cellulose dissolution. This IL has high dissolving power towards cellulose and durability for recycling. However, the disadvantage of ILs is their high viscosity, which limits the supreme cellulose concentration in IL solutions, and their high cost, hindering their commercialization. The addition of low-viscous, low-cost, and naturally derived co-solvents can reduce the overall viscosity and cost. In this study, rheology experiments were conducted to investigate the flow behavior of cellulose in [mTBNH][OAc] ionic liquid mixed with the green co-solvents such as γ-Valerolactone (GVL), dimethyl isosorbide (DMI), and N,N′-dimethylpropyleneurea (DMPU). A study of the rheology showed that the viscosity reduces at low doses of co-solvent (≤ 50 wt%) but causes the structuring of the cellulose solution and its gelation (or phase separation) at high doses (≥ 50 wt%). The rheological study also indicated that the flow activation energy of cellulose in IL/co-solvent systems is lower than that in pure IL and decays in the order of DMPU > DMI > GVL > DMSO.
期刊介绍：
"Rheologica Acta is the official journal of The European Society of Rheology. The aim of the journal is to advance the science of rheology, by publishing high quality peer reviewed articles, invited reviews and peer reviewed short communications.
The Scope of Rheologica Acta includes:
- Advances in rheometrical and rheo-physical techniques, rheo-optics, microrheology
- Rheology of soft matter systems, including polymer melts and solutions, colloidal dispersions, cement, ceramics, glasses, gels, emulsions, surfactant systems, liquid crystals, biomaterials and food.
- Rheology of Solids, chemo-rheology
- Electro and magnetorheology
- Theory of rheology
- Non-Newtonian fluid mechanics, complex fluids in microfluidic devices and flow instabilities
- Interfacial rheology
Rheologica Acta aims to publish papers which represent a substantial advance in the field, mere data reports or incremental work will not be considered. Priority will be given to papers that are methodological in nature and are beneficial to a wide range of material classes. It should also be noted that the list of topics given above is meant to be representative, not exhaustive. The editors welcome feedback on the journal and suggestions for reviews and comments."
京公网安备 11010802042870号
京ICP备2023020795号-1
分享
求助内容：
应助结果提醒方式：
扫码关注我们
