Maohua Zhang, Zhiyi Li, Lin Du, Zenong Tian, Dazhi Liu
{"title":"弯曲疲劳载荷、干湿循环和 Cl 腐蚀耦合作用下添加纳米颗粒的海工混凝土耐久性研究","authors":"Maohua Zhang, Zhiyi Li, Lin Du, Zenong Tian, Dazhi Liu","doi":"10.1680/jmacr.23.00062","DOIUrl":null,"url":null,"abstract":"The combination of multiple factors in the marine environment will accelerate the corrosion of concrete structures. Unlike earlier studies, who employed alternate experiments to evaluate the endurance of marine concrete with nanoparticles under the combined impacts of bending fatigue load, dry-wet cycles, and Cl- erosion, this paper integrates three elements in each cycle to accomplish the effect of coupling. The dry-wet cycle test of the optimal amount of nano-concrete was simulated in seawater with a concentration of 5% NaCl solution and bending fatigue loads at stress levels of 0.5, 0.6, 0.7 and 0.8 were applied. X-ray diffraction was used to observe the physical phases of the concrete before and after the experiment and to analyse the reasons for the increased durability of the concrete. The results indicated that the nanoparticles enhance the resistance to Cl- erosion during dry-wet cycles and bending fatigue load by making the nano-concrete more durable under the coupling impact of bending fatigue load, dry-wet cycles, and Cl- erosion. The improvement effect is the most obvious when the nano-TiO2 content is 1% and the improvement effect is most obvious when the nano-SiO2 content is 2%, and the improvement effect is better when the nano-TiO2 content is 1% than when the nano-SiO2 content is 2%. In comparison to the compressive zone of concrete, the free Cl- in the tension zone is larger. Microscopic tests showed that nanoparticles increase the content of hydrated calcium silicate in concrete, change the orientation of calcium hydroxide and improve the durability of concrete.","PeriodicalId":1,"journal":{"name":"Accounts of Chemical Research","volume":"2 8","pages":""},"PeriodicalIF":17.7000,"publicationDate":"2024-01-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Study on the durability of marine concrete with nanoparticles under the coupling action of bending fatigue load, dry-wet cycles and Cl−corrosion\",\"authors\":\"Maohua Zhang, Zhiyi Li, Lin Du, Zenong Tian, Dazhi Liu\",\"doi\":\"10.1680/jmacr.23.00062\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"The combination of multiple factors in the marine environment will accelerate the corrosion of concrete structures. Unlike earlier studies, who employed alternate experiments to evaluate the endurance of marine concrete with nanoparticles under the combined impacts of bending fatigue load, dry-wet cycles, and Cl- erosion, this paper integrates three elements in each cycle to accomplish the effect of coupling. The dry-wet cycle test of the optimal amount of nano-concrete was simulated in seawater with a concentration of 5% NaCl solution and bending fatigue loads at stress levels of 0.5, 0.6, 0.7 and 0.8 were applied. X-ray diffraction was used to observe the physical phases of the concrete before and after the experiment and to analyse the reasons for the increased durability of the concrete. The results indicated that the nanoparticles enhance the resistance to Cl- erosion during dry-wet cycles and bending fatigue load by making the nano-concrete more durable under the coupling impact of bending fatigue load, dry-wet cycles, and Cl- erosion. The improvement effect is the most obvious when the nano-TiO2 content is 1% and the improvement effect is most obvious when the nano-SiO2 content is 2%, and the improvement effect is better when the nano-TiO2 content is 1% than when the nano-SiO2 content is 2%. In comparison to the compressive zone of concrete, the free Cl- in the tension zone is larger. Microscopic tests showed that nanoparticles increase the content of hydrated calcium silicate in concrete, change the orientation of calcium hydroxide and improve the durability of concrete.\",\"PeriodicalId\":1,\"journal\":{\"name\":\"Accounts of Chemical Research\",\"volume\":\"2 8\",\"pages\":\"\"},\"PeriodicalIF\":17.7000,\"publicationDate\":\"2024-01-19\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Accounts of Chemical Research\",\"FirstCategoryId\":\"5\",\"ListUrlMain\":\"https://doi.org/10.1680/jmacr.23.00062\",\"RegionNum\":1,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Accounts of Chemical Research","FirstCategoryId":"5","ListUrlMain":"https://doi.org/10.1680/jmacr.23.00062","RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
Study on the durability of marine concrete with nanoparticles under the coupling action of bending fatigue load, dry-wet cycles and Cl−corrosion
The combination of multiple factors in the marine environment will accelerate the corrosion of concrete structures. Unlike earlier studies, who employed alternate experiments to evaluate the endurance of marine concrete with nanoparticles under the combined impacts of bending fatigue load, dry-wet cycles, and Cl- erosion, this paper integrates three elements in each cycle to accomplish the effect of coupling. The dry-wet cycle test of the optimal amount of nano-concrete was simulated in seawater with a concentration of 5% NaCl solution and bending fatigue loads at stress levels of 0.5, 0.6, 0.7 and 0.8 were applied. X-ray diffraction was used to observe the physical phases of the concrete before and after the experiment and to analyse the reasons for the increased durability of the concrete. The results indicated that the nanoparticles enhance the resistance to Cl- erosion during dry-wet cycles and bending fatigue load by making the nano-concrete more durable under the coupling impact of bending fatigue load, dry-wet cycles, and Cl- erosion. The improvement effect is the most obvious when the nano-TiO2 content is 1% and the improvement effect is most obvious when the nano-SiO2 content is 2%, and the improvement effect is better when the nano-TiO2 content is 1% than when the nano-SiO2 content is 2%. In comparison to the compressive zone of concrete, the free Cl- in the tension zone is larger. Microscopic tests showed that nanoparticles increase the content of hydrated calcium silicate in concrete, change the orientation of calcium hydroxide and improve the durability of concrete.
期刊介绍:
Accounts of Chemical Research presents short, concise and critical articles offering easy-to-read overviews of basic research and applications in all areas of chemistry and biochemistry. These short reviews focus on research from the author’s own laboratory and are designed to teach the reader about a research project. In addition, Accounts of Chemical Research publishes commentaries that give an informed opinion on a current research problem. Special Issues online are devoted to a single topic of unusual activity and significance.
Accounts of Chemical Research replaces the traditional article abstract with an article "Conspectus." These entries synopsize the research affording the reader a closer look at the content and significance of an article. Through this provision of a more detailed description of the article contents, the Conspectus enhances the article's discoverability by search engines and the exposure for the research.