弯曲疲劳载荷、干湿循环和 Cl 腐蚀耦合作用下添加纳米颗粒的海工混凝土耐久性研究

IF 1.8 4区 工程技术 Q3 CONSTRUCTION & BUILDING TECHNOLOGY Magazine of Concrete Research Pub Date : 2024-01-19 DOI:10.1680/jmacr.23.00062
Maohua Zhang, Zhiyi Li, Lin Du, Zenong Tian, Dazhi Liu
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引用次数: 0

摘要

海洋环境中多种因素的共同作用会加速混凝土结构的腐蚀。早期研究采用交替实验的方法来评估掺有纳米颗粒的海工混凝土在弯曲疲劳载荷、干湿循环和 Cl- 侵蚀的综合影响下的耐久性,而本文则不同,在每个循环中整合了三个因素,以完成耦合效应。在浓度为 5%NaCl 溶液的海水中模拟了纳米混凝土最佳用量的干湿循环试验,并施加了应力水平为 0.5、0.6、0.7 和 0.8 的弯曲疲劳载荷。利用 X 射线衍射观察了实验前后混凝土的物理相,并分析了混凝土耐久性提高的原因。结果表明,在干湿循环和弯曲疲劳载荷的作用下,纳米颗粒增强了纳米混凝土的抗 Cl- 侵蚀能力,使其在弯曲疲劳载荷、干湿循环和 Cl- 侵蚀的耦合作用下更加耐久。纳米 TiO2 含量为 1%时改善效果最明显,纳米 SiO2 含量为 2%时改善效果最明显,纳米 TiO2 含量为 1%时改善效果优于纳米 SiO2 含量为 2%时。与混凝土的受压区相比,受拉区的游离 Cl- 较大。显微测试表明,纳米颗粒增加了混凝土中水合硅酸钙的含量,改变了氢氧化钙的取向,提高了混凝土的耐久性。
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Study on the durability of marine concrete with nanoparticles under the coupling action of bending fatigue load, dry-wet cycles and Cl−corrosion
The combination of multiple factors in the marine environment will accelerate the corrosion of concrete structures. Unlike earlier studies, who employed alternate experiments to evaluate the endurance of marine concrete with nanoparticles under the combined impacts of bending fatigue load, dry-wet cycles, and Cl- erosion, this paper integrates three elements in each cycle to accomplish the effect of coupling. The dry-wet cycle test of the optimal amount of nano-concrete was simulated in seawater with a concentration of 5% NaCl solution and bending fatigue loads at stress levels of 0.5, 0.6, 0.7 and 0.8 were applied. X-ray diffraction was used to observe the physical phases of the concrete before and after the experiment and to analyse the reasons for the increased durability of the concrete. The results indicated that the nanoparticles enhance the resistance to Cl- erosion during dry-wet cycles and bending fatigue load by making the nano-concrete more durable under the coupling impact of bending fatigue load, dry-wet cycles, and Cl- erosion. The improvement effect is the most obvious when the nano-TiO2 content is 1% and the improvement effect is most obvious when the nano-SiO2 content is 2%, and the improvement effect is better when the nano-TiO2 content is 1% than when the nano-SiO2 content is 2%. In comparison to the compressive zone of concrete, the free Cl- in the tension zone is larger. Microscopic tests showed that nanoparticles increase the content of hydrated calcium silicate in concrete, change the orientation of calcium hydroxide and improve the durability of concrete.
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来源期刊
Magazine of Concrete Research
Magazine of Concrete Research 工程技术-材料科学:综合
CiteScore
4.60
自引率
11.10%
发文量
102
审稿时长
5 months
期刊介绍: For concrete and other cementitious derivatives to be developed further, we need to understand the use of alternative hydraulically active materials used in combination with plain Portland Cement, sustainability and durability issues. Both fundamental and best practice issues need to be addressed. Magazine of Concrete Research covers every aspect of concrete manufacture and behaviour from performance and evaluation of constituent materials to mix design, testing, durability, structural analysis and composite construction.
期刊最新文献
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