使用 ZnO/Co/Cs 混合光催化剂珠高效去除亚甲基蓝染料

Ong Kwang Zhean, Mohd Fadhil Majnis, Mohd Azam Mohd Adnan, Suhanna Natalya Mohd Suhaimy
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摘要

本研究重点介绍了用于纺织业废水处理的混合光催化系统的发展情况。在传统催化剂氧化锌(ZnO)中引入壳聚糖(Cs)和钴(Co),形成混合光催化剂珠。采用溶胶-凝胶法合成了四种不同重量比的 ZnO/Cs (1:1)和 ZnO/Co/Cs (1:1:1、1:2:1 和 2:1:1)珠子。研究了混合 ZnO/Co/Cs 在可见光照射下光催化降解亚甲基蓝(MB)的性能。研究重点是 ZnO/Co/Cs 成分比、辐照时间和光反应器中催化剂负载量对 5 小时辐照时间的影响。结果表明,与其他体系相比,1:1:1 ZnO/Co/Cs 光催化剂珠的降解率最高。在 ZnO/Cs 光催化剂中添加 Co 可提高亚甲基蓝的脱灰比例,从而改善光催化活性。
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Efficient methylene blue dye removal using hybrid ZnO/Co/Cs photocatalyst beads
This study highlighted the developments of the hybrid photocatalytic system for wastewater treatment in the textile industry. Chitosan (Cs) and cobalt (Co) were introduced into the conventional catalyst zinc oxide (ZnO) to form the hybrid photocatalyst beads. Four different weight ratios of ZnO/Cs (1:1) and ZnO/Co/Cs (1:1:1, 1:2:1 and 2:1:1) beads were synthesized by the sol-gel method. The photocatalytic degradation properties of the hybrid ZnO/Co/Cs were investigated under visible light irradiation for methylene blue (MB) photodegradation. The study focused on the effect of ZnO/Co/Cs composition ratio, irradiation time and the amount of catalyst loading in the photoreactor for five hours of exposure time. The result was that the 1:1:1 ZnO/Co/Cs photocatalyst beads had the highest degradation rate compared to the other systems. Adding Co to the ZnO/Cs photocatalyst improved the photocatalytic activity by increasing the decolourization percentage of methylene blue
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