Margareth S. Navarro*, Jacinta Enzweiler, Álvaro P. Crósta, André L. R. Moutinho, Gabriel G. Silva, Christopher D. K. Herd and Patrick J. A. Hill,
{"title":"仅凭 LA-ICP-MS 确定铁陨石的元素特征","authors":"Margareth S. Navarro*, Jacinta Enzweiler, Álvaro P. Crósta, André L. R. Moutinho, Gabriel G. Silva, Christopher D. K. Herd and Patrick J. A. Hill, ","doi":"10.1021/acsearthspacechem.3c00283","DOIUrl":null,"url":null,"abstract":"<p >Chemical composition is an essential aspect of classifying iron meteorites. In this study, we developed and validated a stand-alone procedure for the chemical characterization of iron meteorites using laser ablation-inductively coupled plasma-mass spectrometry (LA-ICP-MS). The adopted innovative approach to the analytical sequence included new features in data reduction software, such as external calibration with more than one measurement standard, yield corrections, and normalization for matrix elements. The obtained results of As, Au, Co, Cr, Cu, Fe, Ga, Ge, Ir, Ni, Os, Pd, Pt, Re, Rh, Ru, and W in nine known iron meteorites agreed with the published values, their recognized chemical classifications, and distribution on normalized chondrite diagrams. Moreover, the results obtained closely correlate with those employed to classify three Brazilian iron meteorites (Conceicao do Tocantins─H, IIAB; Nova Olinda─Ogg, IIAB; and Augusto Pestana─Og, IIIE), which have recently been included in the Meteoritical Bulletin Database. Additionally, we illustrate that LA-ICP-MS elemental mapping, conducted within regions featuring diverse phases of the Augusto Pestana meteorite, serves as a potent tool for chemical classification even without prior knowledge regarding natural structural variations.</p>","PeriodicalId":15,"journal":{"name":"ACS Earth and Space Chemistry","volume":null,"pages":null},"PeriodicalIF":2.9000,"publicationDate":"2024-01-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Elemental Characterization of Iron Meteorites Solely Based on LA-ICP-MS\",\"authors\":\"Margareth S. Navarro*, Jacinta Enzweiler, Álvaro P. Crósta, André L. R. Moutinho, Gabriel G. Silva, Christopher D. K. Herd and Patrick J. A. Hill, \",\"doi\":\"10.1021/acsearthspacechem.3c00283\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p >Chemical composition is an essential aspect of classifying iron meteorites. In this study, we developed and validated a stand-alone procedure for the chemical characterization of iron meteorites using laser ablation-inductively coupled plasma-mass spectrometry (LA-ICP-MS). The adopted innovative approach to the analytical sequence included new features in data reduction software, such as external calibration with more than one measurement standard, yield corrections, and normalization for matrix elements. The obtained results of As, Au, Co, Cr, Cu, Fe, Ga, Ge, Ir, Ni, Os, Pd, Pt, Re, Rh, Ru, and W in nine known iron meteorites agreed with the published values, their recognized chemical classifications, and distribution on normalized chondrite diagrams. Moreover, the results obtained closely correlate with those employed to classify three Brazilian iron meteorites (Conceicao do Tocantins─H, IIAB; Nova Olinda─Ogg, IIAB; and Augusto Pestana─Og, IIIE), which have recently been included in the Meteoritical Bulletin Database. Additionally, we illustrate that LA-ICP-MS elemental mapping, conducted within regions featuring diverse phases of the Augusto Pestana meteorite, serves as a potent tool for chemical classification even without prior knowledge regarding natural structural variations.</p>\",\"PeriodicalId\":15,\"journal\":{\"name\":\"ACS Earth and Space Chemistry\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":2.9000,\"publicationDate\":\"2024-01-23\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"ACS Earth and Space Chemistry\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://pubs.acs.org/doi/10.1021/acsearthspacechem.3c00283\",\"RegionNum\":3,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"ACS Earth and Space Chemistry","FirstCategoryId":"92","ListUrlMain":"https://pubs.acs.org/doi/10.1021/acsearthspacechem.3c00283","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0
摘要
化学成分是铁陨石分类的一个重要方面。在这项研究中,我们开发并验证了利用激光烧蚀-电感耦合等离子体质谱法(LA-ICP-MS)对铁陨石进行化学特征描述的独立程序。所采用的分析序列创新方法包括数据还原软件的新功能,如使用多个测量标准进行外部校准、产量校正和基质元素归一化。所获得的九块已知铁陨石中的砷、金、钴、铬、铜、铁、镓、锗、铁、镍、锇、钯、铂、铼、铑、钌和瓦的含量结果与已公布的数值、其公认的化学分类以及在归一化软玉图上的分布一致。此外,所获得的结果与巴西三块铁陨石(Conceicao do Tocantins─H,IIAB;Nova Olinda─Ogg,IIAB;和 Augusto Pestana─Og,IIIE)的分类结果密切相关,这三块铁陨石最近已被纳入气象公报数据库。此外,我们还说明了在具有奥古斯托-佩斯塔纳陨石不同阶段特征的区域内进行的 LA-ICP-MS 元素绘图,是进行化学分类的有效工具,即使事先不了解自然结构变化也是如此。
Elemental Characterization of Iron Meteorites Solely Based on LA-ICP-MS
Chemical composition is an essential aspect of classifying iron meteorites. In this study, we developed and validated a stand-alone procedure for the chemical characterization of iron meteorites using laser ablation-inductively coupled plasma-mass spectrometry (LA-ICP-MS). The adopted innovative approach to the analytical sequence included new features in data reduction software, such as external calibration with more than one measurement standard, yield corrections, and normalization for matrix elements. The obtained results of As, Au, Co, Cr, Cu, Fe, Ga, Ge, Ir, Ni, Os, Pd, Pt, Re, Rh, Ru, and W in nine known iron meteorites agreed with the published values, their recognized chemical classifications, and distribution on normalized chondrite diagrams. Moreover, the results obtained closely correlate with those employed to classify three Brazilian iron meteorites (Conceicao do Tocantins─H, IIAB; Nova Olinda─Ogg, IIAB; and Augusto Pestana─Og, IIIE), which have recently been included in the Meteoritical Bulletin Database. Additionally, we illustrate that LA-ICP-MS elemental mapping, conducted within regions featuring diverse phases of the Augusto Pestana meteorite, serves as a potent tool for chemical classification even without prior knowledge regarding natural structural variations.
期刊介绍:
The scope of ACS Earth and Space Chemistry includes the application of analytical, experimental and theoretical chemistry to investigate research questions relevant to the Earth and Space. The journal encompasses the highly interdisciplinary nature of research in this area, while emphasizing chemistry and chemical research tools as the unifying theme. The journal publishes broadly in the domains of high- and low-temperature geochemistry, atmospheric chemistry, marine chemistry, planetary chemistry, astrochemistry, and analytical geochemistry. ACS Earth and Space Chemistry publishes Articles, Letters, Reviews, and Features to provide flexible formats to readily communicate all aspects of research in these fields.