二氯(4,7-二甲氧基-1,10-菲罗啉-κ2 N,N′)锌(II)

IUCrData Pub Date : 2024-01-01 DOI:10.1107/S2414314624000373

Nalani P. Rose , Hadi D. Arman , Rafael A. Adrian , M. Weil (Editor)

{"title":"二氯(4,7-二甲氧基-1,10-菲罗啉-κ2 N,N′)锌(II)","authors":"Nalani P. Rose , Hadi D. Arman , Rafael A. Adrian , M. Weil (Editor)","doi":"10.1107/S2414314624000373","DOIUrl":null,"url":null,"abstract":"<div>In the crystal structure of the title compound, the central zinc(II) metal atom is surrounded by two N atoms of a bidentate 4,7-methoxy-1,10-phenanthroline ligand and two chlorido ligands in a distorted tetrahedral coordination environment.</div><div>In the title complex, [ZnCl2(C14H12N2O2)], the ZnII atom is located on a twofold rotation axis and is fourfold coordinated by two chlorido ligands and a bidentate 4,7-methoxy-1,10-phenanthroline ligand in a distorted tetrahedral environment. Weak π–π stacking interactions between adjacent 4,7-dimethoxy-1,10-phenanthroline rings [centroid-to-centroid distances = 3.5969 (11) and 3.7738 (11) Å] contribute to the alignment of the complexes in layers parallel to ( <figure><img></figure> 01). <figure><img><ol><li>Download : Download high-res image (261KB)</li><li>Download : Download full-size image</li></ol></figure> </div>","PeriodicalId":94324,"journal":{"name":"IUCrData","volume":null,"pages":null},"PeriodicalIF":0.0000,"publicationDate":"2024-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Dichlorido(4,7-dimethoxy-1,10-phenanthroline-κ2 N,N′)zinc(II)\",\"authors\":\"Nalani P. Rose , Hadi D. Arman , Rafael A. Adrian , M. Weil (Editor)\",\"doi\":\"10.1107/S2414314624000373\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div>In the crystal structure of the title compound, the central zinc(II) metal atom is surrounded by two N atoms of a bidentate 4,7-methoxy-1,10-phenanthroline ligand and two chlorido ligands in a distorted tetrahedral coordination environment.</div><div>In the title complex, [ZnCl2(C14H12N2O2)], the ZnII atom is located on a twofold rotation axis and is fourfold coordinated by two chlorido ligands and a bidentate 4,7-methoxy-1,10-phenanthroline ligand in a distorted tetrahedral environment. Weak π–π stacking interactions between adjacent 4,7-dimethoxy-1,10-phenanthroline rings [centroid-to-centroid distances = 3.5969 (11) and 3.7738 (11) Å] contribute to the alignment of the complexes in layers parallel to ( <figure><img></figure> 01). <figure><img><ol><li>Download : Download high-res image (261KB)</li><li>Download : Download full-size image</li></ol></figure> </div>\",\"PeriodicalId\":94324,\"journal\":{\"name\":\"IUCrData\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2024-01-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"IUCrData\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://www.sciencedirect.com/org/science/article/pii/S2414314624000324\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"IUCrData","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/org/science/article/pii/S2414314624000324","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}

引用次数: 0

摘要

在标题复合物[ZnCl2(C14H12N2O2)]中，ZnII 原子位于两倍旋转轴上，并在扭曲的四面体环境中与两个酰氯配体和一个双价 4,7-甲氧基-1,10-菲罗啉配体进行四倍配位。相邻的 4,7-二甲氧基-1,10-菲罗啉环之间微弱的 π-π 堆叠相互作用[中心到中心的距离 = 3.5969 (11) 和 3.7738 (11) Å]使复合物平行于 (\overline{2}01)层排列。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

查看原文

微信好友朋友圈 QQ好友复制链接

本刊更多论文

Dichlorido(4,7-dimethoxy-1,10-phenanthroline-κ2 N,N′)zinc(II)

In the crystal structure of the title compound, the central zinc(II) metal atom is surrounded by two N atoms of a bidentate 4,7-methoxy-1,10-phenanthroline ligand and two chlorido ligands in a distorted tetrahedral coordination environment.

In the title complex, [ZnCl₂(C₁₄H₁₂N₂O₂)], the Zn^II atom is located on a twofold rotation axis and is fourfold coordinated by two chlorido ligands and a bidentate 4,7-methoxy-1,10-phenanthroline ligand in a distorted tetrahedral environment. Weak π–π stacking interactions between adjacent 4,7-dimethoxy-1,10-phenanthroline rings [centroid-to-centroid distances = 3.5969 (11) and 3.7738 (11) Å] contribute to the alignment of the complexes in layers parallel to (

01).