黄瓜(Cucumis sativus L.)上乙氰菊酯和吡虫啉复配产品的残留行为和消费者风险评估

IF 0.8 4区 工程技术 Q4 CHEMISTRY, ANALYTICAL Accreditation and Quality Assurance Pub Date : 2024-02-02 DOI:10.1007/s00769-024-01573-2
Sakshi Sharma, Jatiender Kumar Dubey, Sapna Katna, Ajay Sharma, Deepika Shandil, Pankaj Sharma, Nisha Devi, Arvind Kumar, Shubhra Singh, Nimisha Thakur
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引用次数: 0

摘要

研究了2019年种植季期间在黄瓜作物上以推荐剂量(X)和双倍推荐剂量(2X)施用倍氰菊酯和吡虫啉复配制剂的残留行为和消费者风险评估。该组合产品以叶面喷洒的方式施用三次,每次间隔 7 天,第一次在果实初生期施用。在使用改良的 QuEChERS 技术提取和净化样品后,分别使用气相色谱-电子捕获检测器和高压液相色谱法检测了溴氰菊酯和吡虫啉的残留量。倍硫磷在 X 倍和 2 倍剂量下的平均初始残留量分别为 0.69 和 1.41 毫克/千克,在 1.51 和 1.73 天内消散至其浓度的一半,建议的安全等待期分别为 5.73 和 8.34 天;而吡虫啉的初始残留量分别为 0.84 和 1.56 毫克/千克,在 1.29 和 1.51 天内消散至其浓度的一半,建议的安全等待期分别为 5.24 和 7.49 天。在收获时采集的土壤样本中,两种成分的残留量均低于测定水平。以危害商数计算的膳食风险评估结果小于 1,因此,如果按照良好农业规范使用,消费者可以放心使用溴氰菊酯和吡虫啉的复配产品。
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Residue behavior and consumer risk assessment of combination product of betacyfluthrin and imidacloprid on cucumber (Cucumis sativus L.)

Residue behavior and consumer risk assessment of combination of betacyfluthrin and imidacloprid at recommended dose (X) and double the recommended dose (2X) on cucumber crop were studied during kharif season, 2019. The combination product was applied thrice as foliar sprays at 7 days interval with first application at fruit initiation stage. Residues of betacyfluthrin and imidacloprid were detected using gas chromatography-electron capture detector and high pressure liquid chromatography, respectively, after the extraction and clean-up of samples with modified QuEChERS technique. The average initial deposits at X and 2X dose of betacyfluthrin were 0.69 and 1.41 mg kg−1, which dissipated to half of its concentration in 1.51 and 1.73 days with a suggested safe waiting period of 5.73 and 8.34 days whereas, for imidacloprid, initial deposits were 0.84 and 1.56 mg kg−1, which dissipated to half of its concentration in 1.29 and 1.51 days with a suggested safe waiting period of 5.24 and 7.49 days, respectively. Residues in soil samples collected at harvest were found to be below determination level for both components. Dietary risk assessment calculated as hazard quotient came out to be less than 1, thus establishing the safety of combination product of betacyfluthrin and imidacloprid for consumers when used following good agricultural practices.

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来源期刊
Accreditation and Quality Assurance
Accreditation and Quality Assurance 工程技术-分析化学
CiteScore
1.80
自引率
22.20%
发文量
39
审稿时长
6-12 weeks
期刊介绍: Accreditation and Quality Assurance has established itself as the leading information and discussion forum for all aspects relevant to quality, transparency and reliability of measurement results in chemical and biological sciences. The journal serves the information needs of researchers, practitioners and decision makers dealing with quality assurance and quality management, including the development and application of metrological principles and concepts such as traceability or measurement uncertainty in the following fields: environment, nutrition, consumer protection, geology, metallurgy, pharmacy, forensics, clinical chemistry and laboratory medicine, and microbiology.
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