铁铬铝亚层成分对铁铬铝/钇稳定氧化锆复合涂层微观结构和耐腐蚀性的影响

Changda Zhu, Xi Qiu, Yuanming Li, Wei Zhang, Jian Yang, Yilong Zhong, Jiuguo Deng, Mingyang Zhou, Ning Liu, Jijun Yang
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摘要

通过扫描电镜和 XRD 系统研究了 FeCrAl 亚层成分对 FeCrAl/YSZ(钇稳定氧化锆)复合涂层的微观结构和铅铋共晶腐蚀行为的影响。结果表明,作为扩散屏障和结合层的铁铬铝亚层有利于提高涂层的耐腐蚀性。腐蚀后,在 YSZ 和铁铬铝亚层之间的界面上形成了缓慢生长的、连续的富铝氧化物保护层,它能有效地阻止氧原子向内扩散和铁原子向外扩散。特别是,Fe-12Cr-7Al/YSZ 涂层即使在 700 °C 的腐蚀条件下也表现出最佳的耐腐蚀性。阐明了 FeCrAl/YSZ 涂层的微观腐蚀机理。
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Effect of FeCrAl sublayer composition on the microstructure and corrosion resistance of FeCrAl/yttria-stabilized zirconia composite coatings
The effect of FeCrAl sublayer composition on the microstructure and lead-bismuth eutectic corrosion behavior of the FeCrAl/YSZ (Yttria-stabilized zirconia) composite coatings was systematically investigated by SEM and XRD. The results show that the FeCrAl sublayer as a diffusion barrier and a bonding layer is beneficial to improve the corrosion resistance of the coatings. After corrosion, a slow-growing, continuous, and protective Al-rich oxide is formed at the interface between the YSZ and FeCrAl sublayer, which effectively hinders the inward diffusion of oxygen atoms and the outward diffusion of iron atoms. Especially, the Fe-12Cr-7Al/YSZ coating exhibits the best corrosion resistance even after corrosion at 700 °C. The microscopic corrosion mechanism of FeCrAl/YSZ coatings is elucidated.
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