利用非传统加热源萃取(Aegle Marmelos 叶片)色素的作用新见解

IF 1.3 4区 材料科学 Q3 CHEMISTRY, APPLIED Pigment & Resin Technology Pub Date : 2024-02-07 DOI:10.1108/prt-05-2023-0041
Nancy Sobh, Nagla Elshemy, Sahar Nassar, Mona Ali
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引用次数: 0

摘要

目的由于草药和植物的治疗特性以及在自然界中的简单易得性,人类自古以来就用它们来治疗各种弊病和疾病。后来,随着科技的发展,这些植物和草药因其合适的化学成分、丰富的可获得性和易获取性,在一些行业中获得了重要的相关性。Aegle marmelos 是一种可以在自然界中找到的植物。然而,有关这种植物叶片着色行为的文献却很少。设计/方法/途径对影响萃取过程的一些因素进行了研究,发现这些因素对纺织品染色有重大影响,如初始染料浓度、萃取温度、萃取浴 pH 值和萃取时间都发生了变化,以了解它们对颜色萃取的影响。作者报告了微波辐照(MWI)、超声波(USW)和传统加热(CH)这三种加热方法之间的直接比较。根据这些实验设计了两个动力学模型(伪一阶和伪二阶),以研究织物染色过程的机理。此外,实验数据还根据 Langmuir 和 Freundlich 等温线进行了分析。使用 CH 波和 USW 波时,温度分别为 90°C 和 80°C,而使用 MWI 波时,温度为 90%瓦;使用 CH 波和 USW 波时,时间为 120 分钟,而使用 MWI 波时,时间为 40 分钟;聚酰胺、羊毛和棉花的 pH 值分别为 4、5 和 10,这些都是最佳萃取条件。作者还认为,羊毛的吸收率高于其他织物。此外,在低温条件下,MWI 提供了最佳的着色力(K/S)值和均匀性,减少了能源和时间的消耗。着色顺序如下MWI > USW > CH。当使用 CH 和 USW 作为加热源时,羊毛的吸附等温线可以用 Freundlich 等温线很好地拟合,而使用 MWI 时则可以用 Langmuir 方程很好地拟合。研究发现,伪一阶动力学模型能更好地拟合 CH 的实验结果,恒定速率 K1 = -0.000171417 mg/g.min,而伪二阶动力学模型能更好地拟合 MWI(K2 = 38.14022572 mg/g.min)和 USW(K2 = 12.45343554 mg/g.min)的吸收实验结果。通过使用三种不同的加热源(MWI、超声波 [USWW] 和 CH),从 Aegle marmelos 叶子中提取了染料。社会影响在社会方面,由于提取的染料不含任何致癌物质,因此对生态系统和全球社会具有良好的影响。原创性/价值这项工作具有原创性,为纺织业和其他相关领域提供了增值产品。
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New insights into the role of color extraction from (Aegle Marmelos leaf) using a non-traditional heating source

Purpose

Due to herbs and plants’ therapeutic properties and simplicity of availability in nature, humans have used them to treat a variety of maladies and diseases since ancient times. Later, as technology advanced, these plants and herbs gained significant relevance in some industries due to their suitable chemical composition, abundant availability and ease of access. Aegle marmelos is a species of plant that may be found in nature. Yet, little or very little literature was located on the coloration behavior of this plant’s leaves. This study aims to focus on the effect of different parameters on the extraction of colorant from Aegle marmelos leaves.

Design/methodology/approach

Some factors that affected on the extraction processes were examined and found to have significant impacts on the textile dyeing such as the initial dye concentration, extracted temperature, extracted bath pH and extracted time were all changed to see how they affected color extraction. The authors report a direct comparison between three heating methods, namely, microwave irradiation (MWI), ultrasonic waves (USW) and conventional heating (CH). The two kinetic models have been designed (pseudo-first and pseudo-second orders) in the context of these experiments to investigate the mechanism of the dyeing processes for fabrics under study. Also, the experimental data were analyzed according to the Langmuir and Freundlich isotherms.

Findings

From the result, it was discovered these characteristics were found to have a substantial effect on extraction efficiency. Temperature 90°C and 80°C when using CH and USW, respectively, while at 90% watt when using MWI, period 120 min when using CH as well as USW waves, while 40 min when using MWI, and pH 4, 5 and 10 for polyamide, wool and cotton, respectively, were the optimal extraction conditions. Also, the authors can say that wool gives a higher absorption than the other fabric. Additionally, MWI provided the best color strength (K/S) value, and homogeneity, at low temperatures reducing the energy and time consumed. The coloring follows the order: MWI > USW > CH. The adsorption isotherm of wool could be well fitted by Freundlich isotherm when applying CH and USW as a heating source, while it is well fitted by the Langmuir equation in the case of MWI. In the study, it was observed that the pseudo-first-order kinetic model fits better the experimental results of CH with a constant rate K1 = −0.000171417 mg/g.min, while the pseudo-second-order kinetic model fits better the experimental results of absorption of both MWI (K2 = 38.14022572 mg/g.min) and USW (K2 = 12.45343554 mg/g.min).

Research limitations/implications

There is no research limitation for this work. Dye was extracted from Aegle marmelos leaves by applying three different heating sources (MWI, ultrasonic waves [USWW] and CH).

Practical implications

This work has practical applications for the textile industry. It is concluded that using Aegle marmelose leaves can be a possible alternative to extract dye from natural resource by applying new technology to save energy and time and can make the process greener.

Social implications

Socially, it has a good impact on the ecosystem and global community because the extracted dye does not contain any carcinogenic materials.

Originality/value

The work is original and contains value-added products for the textile industry and other confederate fields.

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来源期刊
Pigment & Resin Technology
Pigment & Resin Technology 工程技术-材料科学:膜
CiteScore
2.80
自引率
21.40%
发文量
91
审稿时长
>12 weeks
期刊介绍: The journal looks at developments in: ■Adhesives and sealants ■Curing and coatings ■Wood coatings and preservatives ■Environmentally compliant coating systems and pigments ■Inks for food packaging ■Manufacturing machinery - reactors, mills mixing and dispersing equipment, pumps ■Packaging, labeling and storage ■Plus topical features and news on materials, coatings, industry people, conferences, books and so on ■Raw materials such as pigments, solvents, resins and chemicals ■Testing equipment and procedures
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