Mingyu Zhang, Dong Yan, Rui Xu, Yuqi Tang, Shuangping Xu, Yanqing Qu, Jingyu Xu, Boyu Du, Hongge Jia
{"title":"含氨基配体的铑催化剂[Rh(cod)(TTT)2]的合成及其在苯乙炔聚合中的催化性能","authors":"Mingyu Zhang, Dong Yan, Rui Xu, Yuqi Tang, Shuangping Xu, Yanqing Qu, Jingyu Xu, Boyu Du, Hongge Jia","doi":"10.1007/s12039-023-02246-2","DOIUrl":null,"url":null,"abstract":"<div><p>A new rhodium complex [Rh(cod)(TTT)<sub>2</sub>] was synthesized by [Rh(cod)Cl]<sub>2</sub> as a precursor, and 4,4',4''-(1,3,5-triazine-2,4,6-triyl)trianiline (TTT) as a ligand. Its structure was verified by <sup>1</sup>H and <sup>13</sup>C NMR. The results indicate that the complex shows high activity in phenylacetylene polymerization. It was applied to the polymerization of phenylacetylene with a yield of 45.0% and Mw = 2.26×10<sup>5</sup> at ultra-low rhodium feed ratio ([Rh.]/[M.]=1/60000).</p><h3>Graphical abstract</h3><p>A new rhodium complex [Rh(cod)(TTT)<sub>2</sub>] was synthesized by [Rh(cod)Cl]<sub>2</sub> as a precursor, and 4,4',4''-(1,3,5-triazine-2,4,6-triyl)trianiline (TTT) as a ligand. It was applied to the polymerization of phenylacetylene with a yield of 45.0% and Mw = 2.26×10<sup>5</sup> at ultra-low rhodium feed ratio ([Rh.]/[M.]=1/60000\n</p><div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":616,"journal":{"name":"Journal of Chemical Sciences","volume":null,"pages":null},"PeriodicalIF":1.7000,"publicationDate":"2024-02-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Synthesis of rhodium catalyst [Rh(cod)(TTT)2] with amino group ligand and its catalytic performance for phenylacetylene polymerization\",\"authors\":\"Mingyu Zhang, Dong Yan, Rui Xu, Yuqi Tang, Shuangping Xu, Yanqing Qu, Jingyu Xu, Boyu Du, Hongge Jia\",\"doi\":\"10.1007/s12039-023-02246-2\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>A new rhodium complex [Rh(cod)(TTT)<sub>2</sub>] was synthesized by [Rh(cod)Cl]<sub>2</sub> as a precursor, and 4,4',4''-(1,3,5-triazine-2,4,6-triyl)trianiline (TTT) as a ligand. Its structure was verified by <sup>1</sup>H and <sup>13</sup>C NMR. The results indicate that the complex shows high activity in phenylacetylene polymerization. It was applied to the polymerization of phenylacetylene with a yield of 45.0% and Mw = 2.26×10<sup>5</sup> at ultra-low rhodium feed ratio ([Rh.]/[M.]=1/60000).</p><h3>Graphical abstract</h3><p>A new rhodium complex [Rh(cod)(TTT)<sub>2</sub>] was synthesized by [Rh(cod)Cl]<sub>2</sub> as a precursor, and 4,4',4''-(1,3,5-triazine-2,4,6-triyl)trianiline (TTT) as a ligand. It was applied to the polymerization of phenylacetylene with a yield of 45.0% and Mw = 2.26×10<sup>5</sup> at ultra-low rhodium feed ratio ([Rh.]/[M.]=1/60000\\n</p><div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>\",\"PeriodicalId\":616,\"journal\":{\"name\":\"Journal of Chemical Sciences\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":1.7000,\"publicationDate\":\"2024-02-15\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Chemical Sciences\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://link.springer.com/article/10.1007/s12039-023-02246-2\",\"RegionNum\":4,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Chemical Sciences","FirstCategoryId":"92","ListUrlMain":"https://link.springer.com/article/10.1007/s12039-023-02246-2","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
Synthesis of rhodium catalyst [Rh(cod)(TTT)2] with amino group ligand and its catalytic performance for phenylacetylene polymerization
A new rhodium complex [Rh(cod)(TTT)2] was synthesized by [Rh(cod)Cl]2 as a precursor, and 4,4',4''-(1,3,5-triazine-2,4,6-triyl)trianiline (TTT) as a ligand. Its structure was verified by 1H and 13C NMR. The results indicate that the complex shows high activity in phenylacetylene polymerization. It was applied to the polymerization of phenylacetylene with a yield of 45.0% and Mw = 2.26×105 at ultra-low rhodium feed ratio ([Rh.]/[M.]=1/60000).
Graphical abstract
A new rhodium complex [Rh(cod)(TTT)2] was synthesized by [Rh(cod)Cl]2 as a precursor, and 4,4',4''-(1,3,5-triazine-2,4,6-triyl)trianiline (TTT) as a ligand. It was applied to the polymerization of phenylacetylene with a yield of 45.0% and Mw = 2.26×105 at ultra-low rhodium feed ratio ([Rh.]/[M.]=1/60000
期刊介绍：
Journal of Chemical Sciences is a monthly journal published by the Indian Academy of Sciences. It formed part of the original Proceedings of the Indian Academy of Sciences – Part A, started by the Nobel Laureate Prof C V Raman in 1934, that was split in 1978 into three separate journals. It was renamed as Journal of Chemical Sciences in 2004. The journal publishes original research articles and rapid communications, covering all areas of chemical sciences. A significant feature of the journal is its special issues, brought out from time to time, devoted to conference symposia/proceedings in frontier areas of the subject, held not only in India but also in other countries.
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