各向异性对多孔介质电渗流渗透性的影响:多尺度方法

IF 2.7 3区 工程技术 Q3 ENGINEERING, CHEMICAL Transport in Porous Media Pub Date : 2024-02-13 DOI:10.1007/s11242-024-02060-5
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引用次数: 0

摘要

摘要 多孔介质中的电渗透流动是当代一个重要的研究领域,在各种工程、地质和生物领域都有应用。遵守多孔介质电渗流的达西定律与压力驱动流的达西定律类似,可以得到一个非常重要的物理特性--电渗透性。这项研究旨在利用单相流体流动的多尺度均质化方法,研究壁Zeta电位、Debye长度、固体颗粒形状和优先取向对电渗张量的影响。为了确定从扁球形椭圆体到球形的可能颗粒形状范围,采用了长宽比参数。此外,还探讨了各向异性比和扭曲度。本研究的控制方程包括质量连续性方程、平流-扩散方程、电双层泊松-玻尔兹曼方程以及以完全耦合方式求解电场的拉普拉斯方程。采用双尺度计算均质化技术来模拟受外部电效应影响的流体饱和周期介质。采用有限元方法以耦合方式求解多尺度和多物理场问题。结果表明,固体颗粒的壁zeta电位、长宽比和取向对电渗性有显著影响。此外,主要发现之一是 EDL 厚度对多孔介质的电渗透性、各向异性比和迂回度有重要影响。
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Effect of Anisotropy on the Permeability of Electroosmotic Flow Through Porous Media: Multiscale Approach

Abstract

Electroosmotic flow through porous media is a crucial contemporary research field that finds its application in the areas of various engineering, geological, and biological settings. Obeying Darcy’s law for electroosmotic flow through porous media in similar lines to that of pressure-driven flow yields a very important physical property of electro-permeability. This work aims to examine the influence of wall zeta potential, Debye length, the solid particle shape, and preferential orientation on the electro-permeability tensor using multiscale homogenization methodology for a single-phase fluid flow. For determining the range of possible particle shapes from prolate-oblate ellipsoid to sphere, the parameter of aspect ratio is employed. Additionally, anisotropy ratio and tortuosity have been explored. The governing equations for this study comprise a mass continuity equation, an advection–diffusion equation, a Poisson–Boltzmann equation for electric double layer, and a Laplace equation for solving the electric field in a fully coupled manner. A two-scale computational homogenization technique is employed to model the fluid-saturated periodic media subjected to external electric effects. The finite element approach is adopted to solve the multiscale and multi-physics problem in a coupled manner. The results indicate that the electro-permeability is significantly affected by wall zeta potential, aspect ratio, and orientation of solid particles. Also, one of the major findings is that the EDL thickness has a vital effect on the electro-permeability, anisotropy ratio, and tortuosity of the porous media.

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来源期刊
Transport in Porous Media
Transport in Porous Media 工程技术-工程:化工
CiteScore
5.30
自引率
7.40%
发文量
155
审稿时长
4.2 months
期刊介绍: -Publishes original research on physical, chemical, and biological aspects of transport in porous media- Papers on porous media research may originate in various areas of physics, chemistry, biology, natural or materials science, and engineering (chemical, civil, agricultural, petroleum, environmental, electrical, and mechanical engineering)- Emphasizes theory, (numerical) modelling, laboratory work, and non-routine applications- Publishes work of a fundamental nature, of interest to a wide readership, that provides novel insight into porous media processes- Expanded in 2007 from 12 to 15 issues per year. Transport in Porous Media publishes original research on physical and chemical aspects of transport phenomena in rigid and deformable porous media. These phenomena, occurring in single and multiphase flow in porous domains, can be governed by extensive quantities such as mass of a fluid phase, mass of component of a phase, momentum, or energy. Moreover, porous medium deformations can be induced by the transport phenomena, by chemical and electro-chemical activities such as swelling, or by external loading through forces and displacements. These porous media phenomena may be studied by researchers from various areas of physics, chemistry, biology, natural or materials science, and engineering (chemical, civil, agricultural, petroleum, environmental, electrical, and mechanical engineering).
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