利用冲击管对用于光催化应用的 SrTiO3 纳米粒子的结构、形态和光学特性进行实验研究

Surendhar Sakthivel, Sivaprakash Paramasivam, Periyasamy Velusamy, J. Jerries Infanta, Venkatesan Ragavendran, J. Mayandi, Sonachalam Arumugam, Ikhyun Kim
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摘要

我们研究了动态冲击波在包晶 SrTiO3 (STO) 材料中的作用。我们使用了 XRD、FE-SEM、EDAX、傅立叶变换红外光谱、UV-DRS、XPS 和拉曼光谱来研究该材料。当包晶石样品受到冲击时,其衍射图样未显示出任何晶体结构变化。FE-SEM 结果表明,晶粒尺寸随冲击次数的增加而线性增大。我们使用能量色散 X 射线光谱进行元素分析,结果证实确实存在 SrTiO3 NPs。虽然冲击波的脉冲改变了光学特性,但并不影响分子结构。为了找到未经处理和经过冲击的氮氧化物的光带隙能,我们使用了陶克图关系。带隙能量随着冲击脉冲的增加而变小。冲击波的影响造成了氧空位和表面缺陷,从而降低了带隙能。光催化测试表明,加载了冲击波的 SrTiO3 NPs 在可见光照射下效果更好。研究发现,应力、应变和键长等特性会对光催化应用产生重大影响。此外,还试图为今后的研究提供一个视角。总之,这项研究的目的是为从事 SrTiO3 领域研究的专家提供有价值的见解。
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Experimental investigation of structural, morphological, and optical characteristics of SrTiO3 nanoparticles using a shock tube for photocatalytic applications
We investigated the role of dynamic shock waves in perovskite SrTiO3 (STO) material. XRD, FE-SEM, EDAX, FTIR, UV-DRS, XPS, and Raman spectroscopy were all used to examine the title material. When perovskite sample was loaded with shocks, its diffraction pattern did not show any crystal structure changes. The FE-SEM results suggest that the grain size increased linearly with the number of shocks. We used energy-dispersive X-ray spectroscopy to perform elemental analysis; results confirmed that SrTiO3 NPs were indeed present. Although the impulse of the shock wave changed the optical characteristics, it did not affect the molecular structure. To find the optical band gap energies of untreated and shocked NPs, Tauc plot relationships were used. The band-gap energies got smaller as the shock pulse became more substantial. The impact of shock waves caused oxygen vacancies and surface defects, lowering band gap energy. The test for photocatalytic testing showed that SrTiO3 NPs that are loaded with shock waves worked much better when they were exposed to visible light. The characteristics, including stress, strain, and bond length, were found to significantly influence photocatalytic applications. In addition, attempts were made to provide a viewpoint for future study. Overall, the objective of this research was to provide valuable insights for experts engaged in the field of SrTiO3.
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