通过与 Ti-TiCx/DLC 薄膜滑动来改善 CFRPTFE 在高温下的摩擦学性能

IF 17.7 1区 化学 Q1 CHEMISTRY, MULTIDISCIPLINARY Accounts of Chemical Research Pub Date : 2024-02-08 DOI:10.1177/13506501231209550
Yipan Deng, Yinshui Liu, Hao Pang, Runzhou Xu, Peiling Ke
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引用次数: 0

摘要

聚四氟乙烯(PTFE)已广泛应用于工业领域的密封部件。然而,众所周知,聚四氟乙烯在高温(超过 150 °C)条件下会发生严重磨损,这已成为限制压缩机等重要设备使用寿命的主要缺点。本文提出了一种提高碳纤维增强聚四氟乙烯(CFRPTFE)耐磨性的新解决方案。制备了多层 Ti-TiCx/DLC 薄膜,并将其用作 CFRPTFE 的反面。在高温(200 °C 和 250 °C)下进行了摩擦和磨损试验。未涂层的 17-4PH 钢盘通过不同粒度的砂纸精确抛光后用作基准面(SS80 和 SS7000)。结果发现,通过与 Ti-TiCx/DLC 薄膜的滑动,CFRPTFE 在高温下的摩擦学性能得到了改善。在不同的试验条件下,CFRPTFE 与 DLC 之间的摩擦系数都能保持稳定。与 SS80 相比,CFRPTFE 的磨损率降低了 50%-70%,与 SS7000 相比,磨损率降低了 20%-40%。可以发现,高温下的石墨化转变促进了转移层的形成,与高温下的传统加工表面相比,有助于降低摩擦和磨损。这些重大改进可以延长高温重载应用中 CFRPTFE 运动部件的使用寿命。最后,在微型无油高压压缩机中对所提出的摩擦副进行了工程验证。
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Improving the tribological performance of CFRPTFE at elevated temperature by sliding against Ti-TiCx/DLC film
Polytetrafluoroethylene (PTFE) has been widely used in industrial field for sealing parts. However, it is well known that PTFE is always subject to serious wear at high temperature (over 150 °C), which has become the main drawback limiting serve life of important equipment such as compressors. In this paper, a new solution is proposed for improving the wear resistance of carbon fibers-reinforced PTFE (CFRPTFE). Multilayer Ti-TiCx/DLC film is prepared and used as the counterface of CFRPTFE. Friction and wear tests at high temperature (200 °C and 250 °C) are carried out. The uncoated 17-4PH steel disks precisely polished by abrasive papers with different grain sizes are used as the reference counterface (SS80 and SS7000). It is found that by sliding against Ti-TiCx/DLC film, the tribological behaviors of CFRPTFE at high temperature can be improved. The friction coefficient between CFRPTFE and DLC under different test conditions can be kept in stable state. The wear rates of CFRPTFE reduce by 50%–70% compared to SS80, and reduction of 20%–40% can be observed when compared to SS7000. It can be found that graphitization transition at high temperature promotes the transfer layer formation and contributes to lower friction and lower wear compared to traditional processed counterface at high temperature. These significant improvements can prolong the lifetime of CFRPTFE moving parts used in high-temperature and heavy-load applications. Finally, engineering verification of the proposed friction pair is carried out in miniature oil-free high-pressure compressor.
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来源期刊
Accounts of Chemical Research
Accounts of Chemical Research 化学-化学综合
CiteScore
31.40
自引率
1.10%
发文量
312
审稿时长
2 months
期刊介绍: Accounts of Chemical Research presents short, concise and critical articles offering easy-to-read overviews of basic research and applications in all areas of chemistry and biochemistry. These short reviews focus on research from the author’s own laboratory and are designed to teach the reader about a research project. In addition, Accounts of Chemical Research publishes commentaries that give an informed opinion on a current research problem. Special Issues online are devoted to a single topic of unusual activity and significance. Accounts of Chemical Research replaces the traditional article abstract with an article "Conspectus." These entries synopsize the research affording the reader a closer look at the content and significance of an article. Through this provision of a more detailed description of the article contents, the Conspectus enhances the article's discoverability by search engines and the exposure for the research.
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