{"title":"交联聚合物的 z 平均值","authors":"Rolf Bachmann","doi":"10.1002/mats.202300065","DOIUrl":null,"url":null,"abstract":"Stockmayer's formula for the weight average of cross‐linked primary chains was extended to the z‐average degree of polymerization DPz. This average is a function of the weight‐ and z‐average degree of polymerization λw and λz of the primary chain distribution and the branching density α: Higher averages of branched polymers from monomers of type Af and BAf − 1 with functionalities f ⩾ 2 are discussed.This article is protected by copyright. All rights reserved","PeriodicalId":1,"journal":{"name":"Accounts of Chemical Research","volume":"384 6","pages":""},"PeriodicalIF":18.0000,"publicationDate":"2024-02-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"The z‐Average of Cross‐Linked Polymers\",\"authors\":\"Rolf Bachmann\",\"doi\":\"10.1002/mats.202300065\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Stockmayer's formula for the weight average of cross‐linked primary chains was extended to the z‐average degree of polymerization DPz. This average is a function of the weight‐ and z‐average degree of polymerization λw and λz of the primary chain distribution and the branching density α: Higher averages of branched polymers from monomers of type Af and BAf − 1 with functionalities f ⩾ 2 are discussed.This article is protected by copyright. All rights reserved\",\"PeriodicalId\":1,\"journal\":{\"name\":\"Accounts of Chemical Research\",\"volume\":\"384 6\",\"pages\":\"\"},\"PeriodicalIF\":18.0000,\"publicationDate\":\"2024-02-09\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Accounts of Chemical Research\",\"FirstCategoryId\":\"5\",\"ListUrlMain\":\"https://doi.org/10.1002/mats.202300065\",\"RegionNum\":1,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Accounts of Chemical Research","FirstCategoryId":"5","ListUrlMain":"https://doi.org/10.1002/mats.202300065","RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0
摘要
斯托克迈尔的交联主链重量平均值公式被扩展到 z 平均聚合度 DPz。该平均值是主链分布的重量平均聚合度 λw 和 z 平均聚合度 λz 以及支化密度 α 的函数：本文受版权保护。本文受版权保护。
Stockmayer's formula for the weight average of cross‐linked primary chains was extended to the z‐average degree of polymerization DPz. This average is a function of the weight‐ and z‐average degree of polymerization λw and λz of the primary chain distribution and the branching density α: Higher averages of branched polymers from monomers of type Af and BAf − 1 with functionalities f ⩾ 2 are discussed.This article is protected by copyright. All rights reserved
期刊介绍：
Accounts of Chemical Research presents short, concise and critical articles offering easy-to-read overviews of basic research and applications in all areas of chemistry and biochemistry. These short reviews focus on research from the author’s own laboratory and are designed to teach the reader about a research project. In addition, Accounts of Chemical Research publishes commentaries that give an informed opinion on a current research problem. Special Issues online are devoted to a single topic of unusual activity and significance.
Accounts of Chemical Research replaces the traditional article abstract with an article "Conspectus." These entries synopsize the research affording the reader a closer look at the content and significance of an article. Through this provision of a more detailed description of the article contents, the Conspectus enhances the article's discoverability by search engines and the exposure for the research.
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