苯乙烯/1,3-丁二烯橡胶 (SBR) 冷乳液共聚工艺的数字双胞胎

IF 1.8 4区 工程技术 Q3 ENGINEERING, CHEMICAL Macromolecular Reaction Engineering Pub Date : 2024-02-02 DOI:10.1002/mren.202300055
Roymel R. Carpio, Thiago Feital, Maurício M. Câmara, Flávio Gerhardt, Leo Lincoln Oliveira, José Carlos Pinto
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引用次数: 0

摘要

在全球生产的所有合成橡胶中,苯乙烯/1,3-丁二烯橡胶(SBR)是使用最广泛的弹性体,为描述生产该橡胶的乳液共聚过程而开发精确、稳健的动态模型,是实施监测、先进控制和优化策略的基础。关于丁苯橡胶乳液共聚的动态建模已有多项研究,但大多数研究都集中在热条件下,或者像冷条件下那样只有一个半间歇反应器。因此,本研究将重点放在 SBR 冷乳液共聚过程的动态建模上,考虑到一列由 15 个连续搅拌罐反应器组成的反应器,就像许多实际工业现场一样。所开发的动态模型通过使用数字孪生(DT)概念来实现,包括在线读取过程变量和在线调整部分模型参数的自适应策略,同时对反应器组中反应器数量的实时变化的影响也很敏感,这是以前一直被忽视的问题,但在工厂现场却很重要。DT 监测实际工业过程的实际应用说明了所开发工具的鲁棒性和准确性,使其有助于及时发现过程异常,并为未来的先进控制策略开辟了道路。本文受版权保护。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

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Digital Twin for the SBR Cold Emulsion Copolymerization Process

Development of accurate and robust dynamic models for the description of emulsion copolymerization processes is fundamental for the implementation of monitoring, advanced control, and optimization strategies. There are several studies on the dynamic modeling of styrene/1,3-butadiene rubber (SBR) emulsion copolymerization, but most of them focus on hot conditions or only one semi-batch reactor, as in the case of cold conditions. For this reason, the present study focuses on the dynamic modeling of SBR cold emulsion copolymerization processes considering a train of 15 continuous stirred tank reactors, as in many real industrial sites. The developed dynamic model is implemented by using the digital twin (DT) concept, which involves the online reading of process variables and an adaptive strategy for online tuning of some of the model parameters, being also sensitive to the effect of real-time changes on the number of reactors in the train, a subject that has been overlooked previously, but which is important at the plant site. The practical application of the DT for monitoring a real industrial process illustrates the robustness and accuracy of the developed tool, making it useful for opportune detection of process anomalies and opening the way for future advanced control strategies.

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来源期刊
Macromolecular Reaction Engineering
Macromolecular Reaction Engineering 工程技术-高分子科学
CiteScore
2.60
自引率
20.00%
发文量
55
审稿时长
3 months
期刊介绍: Macromolecular Reaction Engineering is the established high-quality journal dedicated exclusively to academic and industrial research in the field of polymer reaction engineering.
期刊最新文献
Monomer Transport by Collisions in (Mini) Emulsion Polymerization, a Personal Perspective Front Cover: Macromol. React. Eng. 4/2024 Masthead: Macromol. React. Eng. 4/2024 Tailoring Polyaniline for Improved Acetaldehyde Detection Determining the Kinetic and Thermodynamic Parameters of Anionic Polymerization of Styrene Using Linear Free‐Energy Relationship
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