{"title":"异构体和立体阻碍在羧基碳硅烷表面活性剂胶束化中的作用","authors":"Tianquan Wu, Hailong Liu, Jinglin Tan","doi":"10.1002/jsde.12744","DOIUrl":null,"url":null,"abstract":"<p>A series of carboxylated carbosilane surfactants with methyl, ethyl, branching CH<sub>3</sub><span></span>, phenyl, and cyclohexyl (Me-Si<sub>2</sub>C-COONa, Et-Si<sub>2</sub>C-COONa, Si<sub>2</sub>C-La-COONa, Ph-Si<sub>2</sub>C-COONa, and Cy-Si<sub>2</sub>C-COONa) were prepared. The effect of isomer and steric hindrance on their micellization in aqueous solution was investigated by surface tension, conductivity, transmission electron microscopy (TEM) and dynamic light scattering (DLS). Si<sub>2</sub>C-La-COONa with branching CH<sub>3</sub><span></span> shows a lower γ<sub>CMC</sub> value and higher the CMC value compared with Et-Si<sub>2</sub>C-COONa. Cy-Si<sub>2</sub>C-COONa with cyclohexyl (41.6 mN m<sup>−1</sup>) and Ph-Si<sub>2</sub>C-COONa with phenyl (43.9 mN m<sup>−1</sup>) have larger γ<sub>CMC</sub> values due to the distinct steric hindrance and hydrophobicity. In aqueous solution, the aggregation behavior of Si<sub>2</sub>C-La-COONa, Cy-Si<sub>2</sub>C-COONa, and Ph-Si<sub>2</sub>C-COONa is enthalpy-driven. However, the micellization process of Me-Si<sub>2</sub>C-COONa and Et-Si<sub>2</sub>C-COONa is governed by the enthalpy-driven at high temperature and entropy-driven at low temperature. DLS and TEM results indicate that the carboxylated carbosilane surfactants can self-assemble into aggregate with hydrodynamic diameters of 50–400 nm.</p>","PeriodicalId":17083,"journal":{"name":"Journal of Surfactants and Detergents","volume":"27 4","pages":"535-545"},"PeriodicalIF":1.6000,"publicationDate":"2024-02-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Role of isomers and steric hindrance in the micellization of carboxylated carbosilane surfactants\",\"authors\":\"Tianquan Wu, Hailong Liu, Jinglin Tan\",\"doi\":\"10.1002/jsde.12744\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>A series of carboxylated carbosilane surfactants with methyl, ethyl, branching CH<sub>3</sub><span></span>, phenyl, and cyclohexyl (Me-Si<sub>2</sub>C-COONa, Et-Si<sub>2</sub>C-COONa, Si<sub>2</sub>C-La-COONa, Ph-Si<sub>2</sub>C-COONa, and Cy-Si<sub>2</sub>C-COONa) were prepared. The effect of isomer and steric hindrance on their micellization in aqueous solution was investigated by surface tension, conductivity, transmission electron microscopy (TEM) and dynamic light scattering (DLS). Si<sub>2</sub>C-La-COONa with branching CH<sub>3</sub><span></span> shows a lower γ<sub>CMC</sub> value and higher the CMC value compared with Et-Si<sub>2</sub>C-COONa. Cy-Si<sub>2</sub>C-COONa with cyclohexyl (41.6 mN m<sup>−1</sup>) and Ph-Si<sub>2</sub>C-COONa with phenyl (43.9 mN m<sup>−1</sup>) have larger γ<sub>CMC</sub> values due to the distinct steric hindrance and hydrophobicity. In aqueous solution, the aggregation behavior of Si<sub>2</sub>C-La-COONa, Cy-Si<sub>2</sub>C-COONa, and Ph-Si<sub>2</sub>C-COONa is enthalpy-driven. However, the micellization process of Me-Si<sub>2</sub>C-COONa and Et-Si<sub>2</sub>C-COONa is governed by the enthalpy-driven at high temperature and entropy-driven at low temperature. DLS and TEM results indicate that the carboxylated carbosilane surfactants can self-assemble into aggregate with hydrodynamic diameters of 50–400 nm.</p>\",\"PeriodicalId\":17083,\"journal\":{\"name\":\"Journal of Surfactants and Detergents\",\"volume\":\"27 4\",\"pages\":\"535-545\"},\"PeriodicalIF\":1.6000,\"publicationDate\":\"2024-02-22\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Surfactants and Detergents\",\"FirstCategoryId\":\"5\",\"ListUrlMain\":\"https://onlinelibrary.wiley.com/doi/10.1002/jsde.12744\",\"RegionNum\":4,\"RegionCategory\":\"工程技术\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"CHEMISTRY, APPLIED\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Surfactants and Detergents","FirstCategoryId":"5","ListUrlMain":"https://onlinelibrary.wiley.com/doi/10.1002/jsde.12744","RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"CHEMISTRY, APPLIED","Score":null,"Total":0}
Role of isomers and steric hindrance in the micellization of carboxylated carbosilane surfactants
A series of carboxylated carbosilane surfactants with methyl, ethyl, branching CH3, phenyl, and cyclohexyl (Me-Si2C-COONa, Et-Si2C-COONa, Si2C-La-COONa, Ph-Si2C-COONa, and Cy-Si2C-COONa) were prepared. The effect of isomer and steric hindrance on their micellization in aqueous solution was investigated by surface tension, conductivity, transmission electron microscopy (TEM) and dynamic light scattering (DLS). Si2C-La-COONa with branching CH3 shows a lower γCMC value and higher the CMC value compared with Et-Si2C-COONa. Cy-Si2C-COONa with cyclohexyl (41.6 mN m−1) and Ph-Si2C-COONa with phenyl (43.9 mN m−1) have larger γCMC values due to the distinct steric hindrance and hydrophobicity. In aqueous solution, the aggregation behavior of Si2C-La-COONa, Cy-Si2C-COONa, and Ph-Si2C-COONa is enthalpy-driven. However, the micellization process of Me-Si2C-COONa and Et-Si2C-COONa is governed by the enthalpy-driven at high temperature and entropy-driven at low temperature. DLS and TEM results indicate that the carboxylated carbosilane surfactants can self-assemble into aggregate with hydrodynamic diameters of 50–400 nm.
期刊介绍：
Journal of Surfactants and Detergents, a journal of the American Oil Chemists’ Society (AOCS) publishes scientific contributions in the surfactants and detergents area. This includes the basic and applied science of petrochemical and oleochemical surfactants, the development and performance of surfactants in all applications, as well as the development and manufacture of detergent ingredients and their formulation into finished products.
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