利用超临界二氧化碳从天然蜡中形成空心固体脂质微颗粒

IF 1.9 4区 农林科学 Q3 CHEMISTRY, APPLIED Journal of the American Oil Chemists Society Pub Date : 2024-02-25 DOI:10.1002/aocs.12805
Purlen Sezer Okur, Deniz Ciftci, Ozan N. Ciftci
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引用次数: 0

摘要

本研究利用基于超临界流体技术的颗粒形成工艺,探索了天然蜡(即蜡烛树蜡(CLW)和棕榈蜡(CW))形成超硬壳空心固体脂质颗粒的潜力。研究了加压二氧化碳中 CLW 和 CW 的熔化行为和体积膨胀与压力的函数关系。随着压力的增加,蜡的熔点呈线性下降,直至某一水平,然后无论压力如何升高,熔点都保持不变。在 140 和 130 巴二氧化碳压力下,CLW 和 CW 的熔点分别下降了 13.0% 和 8.3%。两种蜡的熔点降低与体积膨胀之间呈正相关。在熔化曲线的线性范围内,蜡的体积膨胀率随压力的增加而增加。在 140 bar/68°C 和 130 bar/85°C 时,CLW(7.1%)和 CW(8.5%)的体积膨胀率最高。CLW 和 CW 均可获得表面光滑的中空固体脂质颗粒。原蜡及其颗粒的熔化行为没有差异。增加 SC-CO2 压力会减小空心颗粒的粒径和内部体积。CLW 的 D[4,3] 在 9.3 至 25.4 μm 之间,而 CW 的 D[4,3] 在 8.7 至 34.2 μm 之间。研究发现,CLW 和 CW 是合适的高熔点脂质,可通过 SC-CO2 辅助颗粒形成工艺形成具有超硬保护壳的空心固体脂质颗粒。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

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Formation of hollow solid lipid microparticles from natural waxes using supercritical carbon dioxide

In this study, the potential of natural waxes, namely, candelilla wax (CLW) and carnauba wax (CW), was explored to form extra-hard shell hollow solid lipid particles using a particle formation process based on supercritical fluid technology. Melting behavior and volumetric expansion of CLW and CW in pressurized CO2 were investigated as a function of pressure. The melting point of waxes decreased linearly with increasing pressures up to a certain level; then stayed constant regardless of further elevated pressures. The highest melting point depressions of 13.0% and 8.3% were observed for CLW and CW at 140 and 130 bar CO2 pressure, respectively. A positive correlation between the melting point depression and volumetric expansion was observed for both waxes. The volumetric expansion of waxes increased with increasing pressures within the linear range of the melting curves. The highest volumetric expansion was achieved at 140 bar/68°C and 130 bar/85°C for CLW (7.1%) and CW (8.5%), respectively. Hollow solid lipid particles with smooth surfaces were obtained from both CLW and CW. There was no difference between the melting behavior of the original waxes and their particles. Increasing SC-CO2 pressure decreased the particle size and inner volume of the hollow particles. D[4,3] of CLW ranged between 9.3 and 25.4 μm, whereas it ranged between 8.7 and 34.2 μm for CW. CLW and CW were found to be suitable high-melting lipids to form hollow solid lipid particles via SC-CO2-assisted particle formation process to develop hollow solid lipid particles with an extra-hard protective shell.

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来源期刊
CiteScore
4.10
自引率
5.00%
发文量
95
审稿时长
2.4 months
期刊介绍: The Journal of the American Oil Chemists’ Society (JAOCS) is an international peer-reviewed journal that publishes significant original scientific research and technological advances on fats, oils, oilseed proteins, and related materials through original research articles, invited reviews, short communications, and letters to the editor. We seek to publish reports that will significantly advance scientific understanding through hypothesis driven research, innovations, and important new information pertaining to analysis, properties, processing, products, and applications of these food and industrial resources. Breakthroughs in food science and technology, biotechnology (including genomics, biomechanisms, biocatalysis and bioprocessing), and industrial products and applications are particularly appropriate. JAOCS also considers reports on the lipid composition of new, unique, and traditional sources of lipids that definitively address a research hypothesis and advances scientific understanding. However, the genus and species of the source must be verified by appropriate means of classification. In addition, the GPS location of the harvested materials and seed or vegetative samples should be deposited in an accredited germplasm repository. Compositional data suitable for Original Research Articles must embody replicated estimate of tissue constituents, such as oil, protein, carbohydrate, fatty acid, phospholipid, tocopherol, sterol, and carotenoid compositions. Other components unique to the specific plant or animal source may be reported. Furthermore, lipid composition papers should incorporate elements of year­to­year, environmental, and/ or cultivar variations through use of appropriate statistical analyses.
期刊最新文献
Issue Information Issue Information Microfluidization outperforms homogenization: Optimizing stability and bioaccessibility in krill oil emulsions Issue Information JAOCS special issue on advancement in plant protein-based emulsions
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