I. I. Kuznetsova, O. K. Lebedeva, D. Yu. Kultin, N. S. Perov, L. M. Kustov
{"title":"表面微观结构对非晶钴基 Co-Si-Fe-Cr-Al 合金耐腐蚀性和磁性能的影响","authors":"I. I. Kuznetsova, O. K. Lebedeva, D. Yu. Kultin, N. S. Perov, L. M. Kustov","doi":"10.1134/S0012500823700222","DOIUrl":null,"url":null,"abstract":"<p>The surface of an amorphous cobalt-based alloy with a nominal composition of Co75Si15Fe5Cr4.5Al0.5 was modified with nanostructures by anodizing in an ionic liquid—1-butyl-3-methylimidazolium bis(trifluoromethanesulfonyl)imide. The magnetic (specific saturation magnetization and coercive force) and corrosion (corrosion potential and resistance) characteristics of an amorphous alloy before and after electrochemical modification of the surface with nanostructures have been compared. Modification of the alloy surface partially changes its magnetic properties. After corrosion tests, an increase in the coercive force is observed. Corrosion tests were carried out using the polarization curve method in Ringer’s solution. The corrosion resistance of alloys modified with oxide nanostructures is higher than the corrosion resistance of an abrasive-treated alloy. The increase in corrosion resistance is determined mainly by the presence of nanostructures.</p>","PeriodicalId":530,"journal":{"name":"Doklady Chemistry","volume":"514 2","pages":"35 - 41"},"PeriodicalIF":0.8000,"publicationDate":"2024-03-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Effect of Surface Microstructure on the Corrosion Resistance and Magnetic Properties of an Amorphous Cobalt-Based Co–Si–Fe–Cr–Al Alloy\",\"authors\":\"I. I. Kuznetsova, O. K. Lebedeva, D. Yu. Kultin, N. S. Perov, L. M. Kustov\",\"doi\":\"10.1134/S0012500823700222\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>The surface of an amorphous cobalt-based alloy with a nominal composition of Co75Si15Fe5Cr4.5Al0.5 was modified with nanostructures by anodizing in an ionic liquid—1-butyl-3-methylimidazolium bis(trifluoromethanesulfonyl)imide. The magnetic (specific saturation magnetization and coercive force) and corrosion (corrosion potential and resistance) characteristics of an amorphous alloy before and after electrochemical modification of the surface with nanostructures have been compared. Modification of the alloy surface partially changes its magnetic properties. After corrosion tests, an increase in the coercive force is observed. Corrosion tests were carried out using the polarization curve method in Ringer’s solution. The corrosion resistance of alloys modified with oxide nanostructures is higher than the corrosion resistance of an abrasive-treated alloy. The increase in corrosion resistance is determined mainly by the presence of nanostructures.</p>\",\"PeriodicalId\":530,\"journal\":{\"name\":\"Doklady Chemistry\",\"volume\":\"514 2\",\"pages\":\"35 - 41\"},\"PeriodicalIF\":0.8000,\"publicationDate\":\"2024-03-08\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Doklady Chemistry\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://link.springer.com/article/10.1134/S0012500823700222\",\"RegionNum\":4,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Doklady Chemistry","FirstCategoryId":"92","ListUrlMain":"https://link.springer.com/article/10.1134/S0012500823700222","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
Effect of Surface Microstructure on the Corrosion Resistance and Magnetic Properties of an Amorphous Cobalt-Based Co–Si–Fe–Cr–Al Alloy
The surface of an amorphous cobalt-based alloy with a nominal composition of Co75Si15Fe5Cr4.5Al0.5 was modified with nanostructures by anodizing in an ionic liquid—1-butyl-3-methylimidazolium bis(trifluoromethanesulfonyl)imide. The magnetic (specific saturation magnetization and coercive force) and corrosion (corrosion potential and resistance) characteristics of an amorphous alloy before and after electrochemical modification of the surface with nanostructures have been compared. Modification of the alloy surface partially changes its magnetic properties. After corrosion tests, an increase in the coercive force is observed. Corrosion tests were carried out using the polarization curve method in Ringer’s solution. The corrosion resistance of alloys modified with oxide nanostructures is higher than the corrosion resistance of an abrasive-treated alloy. The increase in corrosion resistance is determined mainly by the presence of nanostructures.
期刊介绍:
Doklady Chemistry is a journal that publishes new research in chemistry and chemical engineering of great significance. Initially the journal was a forum of the Russian Academy of Science and published only best contributions from Russia in the form of short articles. Now the journal welcomes submissions from any country in the English or Russian language. Every manuscript must be recommended by Russian or foreign members of the Russian Academy of Sciences.