表面微观结构对非晶钴基 Co-Si-Fe-Cr-Al 合金耐腐蚀性和磁性能的影响

IF 0.8 4区 化学 Q4 CHEMISTRY, MULTIDISCIPLINARY Doklady Chemistry Pub Date : 2024-03-08 DOI:10.1134/S0012500823700222
I. I. Kuznetsova, O. K. Lebedeva, D. Yu. Kultin, N. S. Perov, L. M. Kustov
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摘要

摘要 通过在离子液体-1-丁基-3-甲基咪唑鎓双(三氟甲磺酰)亚胺中阳极氧化,对标称成分为 Co75Si15Fe5Cr4.5Al0.5 的非晶钴基合金表面进行了纳米结构修饰。比较了纳米结构电化学改性前后无定形合金表面的磁性(比饱和磁化率和矫顽力)和腐蚀性(腐蚀电位和耐腐蚀性)。合金表面的改性部分改变了其磁性能。腐蚀试验后,观察到矫顽力增加。在林格氏溶液中使用极化曲线法进行了腐蚀试验。经氧化物纳米结构修饰的合金的耐腐蚀性高于经研磨处理的合金。耐腐蚀性的提高主要取决于纳米结构的存在。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

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Effect of Surface Microstructure on the Corrosion Resistance and Magnetic Properties of an Amorphous Cobalt-Based Co–Si–Fe–Cr–Al Alloy

The surface of an amorphous cobalt-based alloy with a nominal composition of Co75Si15Fe5Cr4.5Al0.5 was modified with nanostructures by anodizing in an ionic liquid—1-butyl-3-methylimidazolium bis(trifluoromethanesulfonyl)imide. The magnetic (specific saturation magnetization and coercive force) and corrosion (corrosion potential and resistance) characteristics of an amorphous alloy before and after electrochemical modification of the surface with nanostructures have been compared. Modification of the alloy surface partially changes its magnetic properties. After corrosion tests, an increase in the coercive force is observed. Corrosion tests were carried out using the polarization curve method in Ringer’s solution. The corrosion resistance of alloys modified with oxide nanostructures is higher than the corrosion resistance of an abrasive-treated alloy. The increase in corrosion resistance is determined mainly by the presence of nanostructures.

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来源期刊
Doklady Chemistry
Doklady Chemistry 化学-化学综合
CiteScore
1.20
自引率
12.50%
发文量
7
审稿时长
6-12 weeks
期刊介绍: Doklady Chemistry is a journal that publishes new research in chemistry and chemical engineering of great significance. Initially the journal was a forum of the Russian Academy of Science and published only best contributions from Russia in the form of short articles. Now the journal welcomes submissions from any country in the English or Russian language. Every manuscript must be recommended by Russian or foreign members of the Russian Academy of Sciences.
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