田间低吨位甲醇生产装置

Yu. V. Zagashvili, Aleksey M. Kuzmin, Vasily N. Efremov
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摘要

介绍了野外生产条件下低吨位甲醇生产装置的概念。所开发的小型可运输装置可确保运行的安全性、可靠性和可维护性,基本产能为每年 5000 吨原料甲醇。技术流程包括两个主要阶段:首先,通过用空气对制备好的天然气进行部分氧化获得合成气,然后将合成气送入甲醇合成联合装置的多反应器级联。装置的主要设备是家用三组分(天然气-空气-化学处理水)合成气发生器(SGG),包括:混合头、点火装置、燃烧室、注水装置、蒸发室。介绍了与 SGG 结合的合成气技术综合体,说明了 SGG 的尺寸、参数和性能,并提供了天然气部分氧化以获得用于合成甲醇的氮压合成气的数值模拟数据。开发了一个简化的甲醇合成技术综合体,其中包括一个直流多反应器级联,在每个反应器之后释放原料甲醇,并对合成原料甲醇的级联进行了数值建模。研究结果确定了碳氧化物转化为甲醇的程度,从而可以评估是否需要采用转化率高达 60%、每 1000 nm3/h 天然气可生产约 800-900 kg/h 原料甲醇的三反应器级联技术。实验数据与安装设备的物料平衡计算相吻合。
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LOW-TONNAGE METHANOL PRODUCTION PLANT IN FIELD CONDITIONS
The concept of a low-tonnage methanol production plant in field production conditions is presented. The developed small-sized transportable installation ensures safety, reliability and maintainability in operation with a base capacity of 5,000 t of raw methanol per year. The technological process consists of two main stages: first, synthesis gas is obtained by partial oxidation of the prepared natural gas with air, and then synthesis gas is fed into a multi-reactor cascade of the methanol synthesis complex. The main apparatus of the installation is a domestic three-component (natural gas – air – chemically treated water) synthesis gas generator (SGG), which includes: mixing head, ignition device, combustion chamber, water injection unit, evaporation chamber. The technological complex of synthesis gas with SGG binding is described, the dimensions, parameters and performance of SGG are indicated, data from numerical modeling of partial oxidation of natural gas to obtain nitrogen-ballasted synthesis gas for the synthesis of methanol are presented. A simplified technological complex for the synthesis of methanol has been developed, which includes a direct-flow multi-reactor cascade with the release of raw methanol after each reactor, and numerical modeling of the cascade of synthesis of raw methanol has been carried out. As a result of the research, the degrees of conversion of carbon oxides into methanol were determined, which made it possible to assess the need for application of a three-reactor cascade with a degree of conversion up to 60 % and with a specific capacity of about 800–900 kg/h of raw methanol per 1000 nm3/h of natural gas. Experimental laboratory data are presented, which coincide with the calculations of the material balances of the installation devices.
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