(10E,15Z)-12-(二甲基磺酰基)-9,13-二羟基十八碳-10,15-二烯酸酯

Molbank Pub Date : 2024-03-03 DOI:10.3390/m1784

Haruka Nishino, Bo-Tao Zhang, Hajime Uchida, Michiya Kamio, Hiroshi Nagai, Masayuki Satake

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摘要

从冲绳蓝藻 Okeania hirsuta 中分离出了一种新型氧化脂素，即 Okeanoate（1）。根据一维和二维核磁共振以及高分辨率质谱等光谱数据，阐明了 1 的结构。这是第一种在碳氢链中间含有二甲基锍分子的氧化脂素。

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(10E,15Z)-12-(Dimethylsulfonio)-9,13-dihydroxyoctadeca-10,15-dienoate

A novel oxylipin, okeanoate (1), was isolated from the Okinawan cyanobacterium Okeania hirsuta. The structure of 1 was elucidated based on spectroscopic data including 1D and 2D NMR, as well as high-resolution mass spectrometry. This is the first oxylipin with a dimethylsulfonium moiety in the middle of the hydrocarbon chain.

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