亚洲和撒哈拉尘埃的显微分析和矿物学

IF 2.5 4区 化学 Q3 CHEMISTRY, ANALYTICAL Journal of Analytical Science and Technology Pub Date : 2024-03-13 DOI:10.1186/s40543-024-00425-5
Gi Young Jeong
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引用次数: 0

摘要

矿物尘埃从沙漠源头远距离飘移,与地球环境相互作用。要了解这种相互作用,就必须了解单个尘埃颗粒的矿物学和微观结构。在此,我总结了尘埃粒子电子显微镜的最新发现,重点是亚洲和撒哈拉尘埃。尘埃粒子是粘土和非粘土矿物的异质混合物。粘土矿物占矿物尘埃质量的一半以上。细小的粘土矿物颗粒形成自己的集合体,包裹在粗糙的非粘土矿物上,或成为复合颗粒的基质。最丰富的粘土矿物是伊利石-直闪石系列粘土矿物(ISCMs),以伊利石和层间伊利石-直闪石为主。撒哈拉尘埃有别于亚洲尘埃,因为它含有大量的白云石和六方高岭石。常见的非粘土硅酸盐有石英、钾长石和富含 Na 的斜长石。撒哈拉尘埃中的无定形二氧化硅与粘土有关。方解石既有纳米纤维,也有粗大颗粒,与大气中的酸反应沉淀出石膏。铁氧化物和钛氧化物的亚微粒散布在尘埃颗粒的细小基质中。ISCM、绿泥石、黑云母和铁氧化物是偏远生态系统的铁载体。尘埃粒子的形状近似椭圆体,其长宽比随着粘土含量的增加而增大。通过对尘埃颗粒进行矿物学分类,可以确定极少量样本的主要矿物成分。本文从环境角度讨论了尘埃粒子的组成矿物学,并简要介绍了尘埃粒子来源地区的矿物地质背景。
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Microanalysis and mineralogy of Asian and Saharan dust
Mineral dust is transported over long distances from desert sources, interacting with Earth environments. The mineralogy and microstructures of individual dust particles are required to understand the interactions. Here, I summarize recent findings from electron microscopy of dust particles, focusing on Asian and Saharan dust. Dust particles are heterogeneous mixtures of clay and nonclay minerals. Clay minerals account for more than half of the mass of mineral dust. Fine grains of clay minerals form their own aggregates, coat coarse nonclay minerals, or become a matrix of composite particles. The most abundant clay minerals are illite‒smectite series clay minerals (ISCMs) dominated by illite and interstratified illite‒smectite. Saharan dust is distinct from Asian dust by the high contents of palygorskite and hexagonal kaolinite. Common nonclay silicates are quartz, K-feldspar, and Na-rich plagioclase. Amorphous silica is associated with clays in Saharan dust. Calcite occurs as nanofibers as well as coarse grains, reacting with atmospheric acids to precipitate gypsum. The submicron grains of iron oxides and titanium oxides are scattered through the fine matrix of dust particles. ISCMs, chlorite, biotite, and iron oxides are iron carriers to remote ecosystems. The shapes of dust particles approximate ellipsoids whose aspect ratios increase with clay contents. The mineralogical classification of dust particles has led to the determination of the bulk mineral composition of a very small quantity of samples. The constituent mineralogy of dust particles is discussed in an environmental context with a brief introduction of the geological backgrounds of the minerals in their source areas.
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来源期刊
Journal of Analytical Science and Technology
Journal of Analytical Science and Technology Environmental Science-General Environmental Science
CiteScore
4.00
自引率
4.20%
发文量
39
审稿时长
13 weeks
期刊介绍: The Journal of Analytical Science and Technology (JAST) is a fully open access peer-reviewed scientific journal published under the brand SpringerOpen. JAST was launched by Korea Basic Science Institute in 2010. JAST publishes original research and review articles on all aspects of analytical principles, techniques, methods, procedures, and equipment. JAST’s vision is to be an internationally influential and widely read analytical science journal. Our mission is to inform and stimulate researchers to make significant professional achievements in science. We aim to provide scientists, researchers, and students worldwide with unlimited access to the latest advances of the analytical sciences.
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