Phase diagram of ternary Co–Fe–Ge system (I): Experimental

Co–Fe–Ge is an important material system for magnetic and catalyst applications. However, phase equilibria information of the Co–Fe–Ge ternary system is limited. Ternary Co–Fe–Ge alloys equilibrated at 950 °C were prepared. The microstructures, chemical compositions and crystal structure of each phase were determined. The phase equilibria isothermal section at 950 °C of the Co–Fe–Ge ternary system was then proposed. A continuous solid solution phase was formed between the Co₅Ge₃ and Fe₅Ge₃ phases and was labeled the β(Co,Fe)₅Ge₃ phase. There are five three-phase regions in the system at 950 °C. A wide α₂ single-phase, and liquid phase regions with large composition ranges being confirmed at the Ge-poor and Ge-rich sides, respectively.