高价碘试剂和 m-CPBA 介导的氧化转化的最新进展

IF 1.7 3区化学 Q3 CHEMISTRY, ORGANIC Current Organic Chemistry Pub Date : 2024-03-14 DOI:10.2174/0113852728296345240215111730

Ravi Varala, Vittal Seema, Mohammed Amanullah, S. Ramanaiah, Mohammed Mujahid Allam

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引用次数: 0

摘要

:在现有的几种过氧化物中，间氯过苯甲酸（mCPBA）是一种高效的氧化试剂，可用于多种氧化转化，如各种官能团的氧化、碳-碳、碳-异键的形成、杂环的形成、杂芳基化、氧化交叉偶联、内酯化、氧化脱芳基化、α-氧代或α-乙酰氧代、氧化 C-C 键活化以及其他杂项反应。本综述旨在批判性地讨论 mCPBA 与高价碘/碘试剂自 2015 年年中至今在有机合成中的重大贡献。

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Recent Advances in Hypervalent Iodine Reagents and m-CPBA Mediated Oxidative Transformations

: Among the several peroxides available, meta-chloroperbenzoic acid (mCPBA) plays an efficient role of oxidizing reagent and is used for many oxidative transformations, such as oxidation of various functional groups, carbon-carbon, carbon-hetero bond formation, heterocyclic ring formation, heteroarylation, oxidative cross-coupling, lactonization, oxidative dearomatization, α-oxytosylation or α-acetoxylation, oxidative C-C bond activation and in other miscellaneous reactions. The purpose of this review is to critically discuss the significant contributions of mCPBA along with hypervalent iodine/iodine reagents in organic synthesis from mid-2015 to date.

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来源期刊

Current Organic Chemistry 化学-有机化学

CiteScore

3.70

自引率

7.70%

发文量

审稿时长

1 months

期刊介绍： Current Organic Chemistry aims to provide in-depth/mini reviews on the current progress in various fields related to organic chemistry including bioorganic chemistry, organo-metallic chemistry, asymmetric synthesis, heterocyclic chemistry, natural product chemistry, catalytic and green chemistry, suitable aspects of medicinal chemistry and polymer chemistry, as well as analytical methods in organic chemistry. The frontier reviews provide the current state of knowledge in these fields and are written by chosen experts who are internationally known for their eminent research contributions. The Journal also accepts high quality research papers focusing on hot topics, highlights and letters besides thematic issues in these fields. Current Organic Chemistry should prove to be of great interest to organic chemists in academia and industry, who wish to keep abreast with recent developments in key fields of organic chemistry.