{"title":"具有不同烷基链长度的卟啉铁(III)氯化物的液晶行为","authors":"Dumrongsak Aryuwananon, Suttinun Phongtamrug, Buncha Pulpoka","doi":"10.1142/s1088424624500032","DOIUrl":null,"url":null,"abstract":"<p>Two novel porphyrin liquid crystals were designed and synthesized. Their structures were characterized by NMR, FT-IR, UV-visible, and mass spectroscopies. The liquid crystalline properties were investigated by DSC, POM and XRD analyses. The C<span><math altimg=\"eq-00001.gif\" display=\"inline\" overflow=\"scroll\"><msub><mrow></mrow><mrow><mn>1</mn><mn>2</mn></mrow></msub></math></span><span></span> and C<span><math altimg=\"eq-00002.gif\" display=\"inline\" overflow=\"scroll\"><msub><mrow></mrow><mrow><mn>1</mn><mn>8</mn></mrow></msub></math></span><span></span> alkyl chains porphyrin iron(III) complex (<b>1-2</b>) displayed three liquid crystalline transitions in a wide temperature range. Both long alkyl chain porphyrin iron(III) complexes were exhibited a columnar mesophase type.</p>","PeriodicalId":16876,"journal":{"name":"Journal of Porphyrins and Phthalocyanines","volume":"32 1","pages":""},"PeriodicalIF":0.9000,"publicationDate":"2024-02-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Liquid crystalline behaviors of porphyrin iron(III) chloride complexes with different alkyl chain lengths\",\"authors\":\"Dumrongsak Aryuwananon, Suttinun Phongtamrug, Buncha Pulpoka\",\"doi\":\"10.1142/s1088424624500032\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>Two novel porphyrin liquid crystals were designed and synthesized. Their structures were characterized by NMR, FT-IR, UV-visible, and mass spectroscopies. The liquid crystalline properties were investigated by DSC, POM and XRD analyses. The C<span><math altimg=\\\"eq-00001.gif\\\" display=\\\"inline\\\" overflow=\\\"scroll\\\"><msub><mrow></mrow><mrow><mn>1</mn><mn>2</mn></mrow></msub></math></span><span></span> and C<span><math altimg=\\\"eq-00002.gif\\\" display=\\\"inline\\\" overflow=\\\"scroll\\\"><msub><mrow></mrow><mrow><mn>1</mn><mn>8</mn></mrow></msub></math></span><span></span> alkyl chains porphyrin iron(III) complex (<b>1-2</b>) displayed three liquid crystalline transitions in a wide temperature range. Both long alkyl chain porphyrin iron(III) complexes were exhibited a columnar mesophase type.</p>\",\"PeriodicalId\":16876,\"journal\":{\"name\":\"Journal of Porphyrins and Phthalocyanines\",\"volume\":\"32 1\",\"pages\":\"\"},\"PeriodicalIF\":0.9000,\"publicationDate\":\"2024-02-15\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Porphyrins and Phthalocyanines\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://doi.org/10.1142/s1088424624500032\",\"RegionNum\":4,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Porphyrins and Phthalocyanines","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.1142/s1088424624500032","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
Liquid crystalline behaviors of porphyrin iron(III) chloride complexes with different alkyl chain lengths
Two novel porphyrin liquid crystals were designed and synthesized. Their structures were characterized by NMR, FT-IR, UV-visible, and mass spectroscopies. The liquid crystalline properties were investigated by DSC, POM and XRD analyses. The C and C alkyl chains porphyrin iron(III) complex (1-2) displayed three liquid crystalline transitions in a wide temperature range. Both long alkyl chain porphyrin iron(III) complexes were exhibited a columnar mesophase type.
期刊介绍：
The Journal of Porphyrins and Phthalocyanines (JPP) covers research in the chemistry, physics, biology and technology of porphyrins, phthalocyanines and related macrocycles. Research papers, review articles and short communications deal with the synthesis, spectroscopy, processing and applications of these compounds.
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