M. M. Kurmach, D. V. Kyryliuk, A. O. Samotoi, S. O. Sotnik, P. S. Yaremov, O. V. Shvets, N. D. Shcherban
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Catalytic Properties of Hierarchical CsAlTi-BEA Zeolites in the Process of Conversion of Styrene with Co2 for Cyclic Carbonate Formation
Hierarchical CsAlTi-BEA zeolites, due to the presence of a high concentration of Lewis acid sites formed by tetrahedrally coordinated Ti4+ ions in the zeolite structure and the neutralization of Brønsted acid sites by Cs+ cations, exhibit high catalytic activity in the tandem reaction of cyclic carbonate formation from styrene in the presence of tert-butyl hydroperoxide under CO2 pressure. The conversion of styrene into epoxide and further into carbonate increases with the content of titanium in the samples, while the selectivity for the cyclic carbonate increases with the content of cesium.
期刊介绍：
Theoretical and Experimental Chemistry is a journal for the rapid publication of research communications and reviews on modern problems of physical chemistry such as:
a) physicochemical bases, principles, and methods for creation of novel processes, compounds, and materials;
b) physicochemical principles of chemical process control, influence of external physical forces on chemical reactions;
c) physical nanochemistry, nanostructures and nanomaterials, functional nanomaterials, size-dependent properties of materials.
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