Jae-Wan Choi, Woo-Hyuk Son, Yun-Hae Kim, Sung-Youl Bae
{"title":"添加三苯基膦对快速固化环氧酸酐 CFRP 系统的影响","authors":"Jae-Wan Choi, Woo-Hyuk Son, Yun-Hae Kim, Sung-Youl Bae","doi":"10.1142/s0217984924410094","DOIUrl":null,"url":null,"abstract":"<p>In this study, we investigated the impact of adding Triphenylphosphine (TPP) at concentrations of 1<span><math altimg=\"eq-00001.gif\" display=\"inline\" overflow=\"scroll\"><mspace width=\".17em\"></mspace></math></span><span></span>wt.%, 3<span><math altimg=\"eq-00002.gif\" display=\"inline\" overflow=\"scroll\"><mspace width=\".17em\"></mspace></math></span><span></span>wt.%, and 5<span><math altimg=\"eq-00003.gif\" display=\"inline\" overflow=\"scroll\"><mspace width=\".17em\"></mspace></math></span><span></span>wt.% to an epoxy-anhydride system that displays, a degradation in mechanical properties at high temperatures. We conducted an analysis of cure behavior using differential scanning calorimetry and evaluated flexural, shear, and tensile strengths at room temperature. To assess heat resistance, CFRP specimens were exposed to 100<sup>∘</sup>C for 1<span><math altimg=\"eq-00004.gif\" display=\"inline\" overflow=\"scroll\"><mspace width=\".17em\"></mspace></math></span><span></span>h, and tensile strengths were subsequently measured. The addition of 3<span><math altimg=\"eq-00005.gif\" display=\"inline\" overflow=\"scroll\"><mspace width=\".17em\"></mspace></math></span><span></span>wt.% TPP resulted in a 5<span><math altimg=\"eq-00006.gif\" display=\"inline\" overflow=\"scroll\"><mspace width=\".17em\"></mspace></math></span><span></span>min reduction in the time required to reach a 95% degree of cure, but it was observed that mechanical properties at room temperature were compromised. CFRP exposed to 100<sup>∘</sup>C indicated that an increase in TPP content helped mitigate the degradation of mechanical properties.</p>","PeriodicalId":18570,"journal":{"name":"Modern Physics Letters B","volume":"85 1","pages":""},"PeriodicalIF":1.8000,"publicationDate":"2024-03-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Effect of triphenylphosphine addition for the fast curing epoxy-anhydride CFRP system\",\"authors\":\"Jae-Wan Choi, Woo-Hyuk Son, Yun-Hae Kim, Sung-Youl Bae\",\"doi\":\"10.1142/s0217984924410094\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>In this study, we investigated the impact of adding Triphenylphosphine (TPP) at concentrations of 1<span><math altimg=\\\"eq-00001.gif\\\" display=\\\"inline\\\" overflow=\\\"scroll\\\"><mspace width=\\\".17em\\\"></mspace></math></span><span></span>wt.%, 3<span><math altimg=\\\"eq-00002.gif\\\" display=\\\"inline\\\" overflow=\\\"scroll\\\"><mspace width=\\\".17em\\\"></mspace></math></span><span></span>wt.%, and 5<span><math altimg=\\\"eq-00003.gif\\\" display=\\\"inline\\\" overflow=\\\"scroll\\\"><mspace width=\\\".17em\\\"></mspace></math></span><span></span>wt.% to an epoxy-anhydride system that displays, a degradation in mechanical properties at high temperatures. We conducted an analysis of cure behavior using differential scanning calorimetry and evaluated flexural, shear, and tensile strengths at room temperature. To assess heat resistance, CFRP specimens were exposed to 100<sup>∘</sup>C for 1<span><math altimg=\\\"eq-00004.gif\\\" display=\\\"inline\\\" overflow=\\\"scroll\\\"><mspace width=\\\".17em\\\"></mspace></math></span><span></span>h, and tensile strengths were subsequently measured. The addition of 3<span><math altimg=\\\"eq-00005.gif\\\" display=\\\"inline\\\" overflow=\\\"scroll\\\"><mspace width=\\\".17em\\\"></mspace></math></span><span></span>wt.% TPP resulted in a 5<span><math altimg=\\\"eq-00006.gif\\\" display=\\\"inline\\\" overflow=\\\"scroll\\\"><mspace width=\\\".17em\\\"></mspace></math></span><span></span>min reduction in the time required to reach a 95% degree of cure, but it was observed that mechanical properties at room temperature were compromised. CFRP exposed to 100<sup>∘</sup>C indicated that an increase in TPP content helped mitigate the degradation of mechanical properties.</p>\",\"PeriodicalId\":18570,\"journal\":{\"name\":\"Modern Physics Letters B\",\"volume\":\"85 1\",\"pages\":\"\"},\"PeriodicalIF\":1.8000,\"publicationDate\":\"2024-03-23\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Modern Physics Letters B\",\"FirstCategoryId\":\"101\",\"ListUrlMain\":\"https://doi.org/10.1142/s0217984924410094\",\"RegionNum\":4,\"RegionCategory\":\"物理与天体物理\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"PHYSICS, APPLIED\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Modern Physics Letters B","FirstCategoryId":"101","ListUrlMain":"https://doi.org/10.1142/s0217984924410094","RegionNum":4,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"PHYSICS, APPLIED","Score":null,"Total":0}
Effect of triphenylphosphine addition for the fast curing epoxy-anhydride CFRP system
In this study, we investigated the impact of adding Triphenylphosphine (TPP) at concentrations of 1wt.%, 3wt.%, and 5wt.% to an epoxy-anhydride system that displays, a degradation in mechanical properties at high temperatures. We conducted an analysis of cure behavior using differential scanning calorimetry and evaluated flexural, shear, and tensile strengths at room temperature. To assess heat resistance, CFRP specimens were exposed to 100∘C for 1h, and tensile strengths were subsequently measured. The addition of 3wt.% TPP resulted in a 5min reduction in the time required to reach a 95% degree of cure, but it was observed that mechanical properties at room temperature were compromised. CFRP exposed to 100∘C indicated that an increase in TPP content helped mitigate the degradation of mechanical properties.
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