使用硼酸和糯米粉作为添加剂通过无压固态烧结法生产碳化硅陶瓷的可能性

A. Jinnapat, Auamporn Rattanasing, Nithiwach Nawaukkaratharnant, Kritkeaw Somton, K. Dateraksa
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摘要

本研究旨在探讨使用硼酸和糯米粉混合物作为替代添加剂,通过无压固态烧结法在 1800℃ 下生产碳化硅(SiC)陶瓷的成本效益可能性。结果表明,在碳化硅混合物(90 wt%)中添加适当比例(摩尔比 0.5)的硼酸-糯米粉混合物(10 wt%)可提高烧结碳化硅样品的致密性和抗弯强度。然而,增加硼酸/糯米粉的比例会降低密度和抗折强度。5.45 wt% 的碳含量足以去除碳化硅表面的氧化层,改善碳化硅陶瓷的性能。总之,硼酸-糯米粉混合物极有可能用作添加剂,通过无压固态烧结生产致密多孔的碳化硅陶瓷。
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Possibility of using boric acid and glutinous rice flour as additive for producing silicon carbide ceramic via pressureless solid-state sintering
This research aimed to investigate the possibility of using the mixture of boric acid and glutinous rice flour as a cost-efficient alternative additive for producing silicon carbide (SiC) ceramic sintered at 1800℃ via pressureless solid-state sintering. The results indicated that the addition of boric acid- glutinous rice flour mixture (10 wt%) in an appropriate ratio (0.5 by molar ratio) into the SiC mixture (90 wt%) enhanced the densification and flexural strength of sintered SiC samples. However, increasing boric acid/glutinous rice flour ratio reduces density and flexural strength. The 5.45 wt% carbon content was sufficient to remove the oxide layer of the SiC surface and improve the properties of SiC ceramic. In summary, the boric acid-glutinous rice flour mixture has a high potential to be used as an additive for producing dense and porous SiC ceramics via pressureless solid-state sintering.
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