用于人工光合作用的光致发光碳纳米点

Rajie A. Medina, Michael E. Franco, L. M. De Juan‐Corpuz, Ryan D. Corpuz
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摘要

碳点(CD)是一种新兴的碳纳米结构,因其独特的性能和潜在的应用而备受关注。碳点具有非凡的特性,包括光致发光、电化学潜力、与生物体的兼容性、水溶性、化学稳定性和多功能表面特性。光盘的化学结构、粒度和表面功能都会对其光致发光特性产生影响,这也是本综述的重点。本文讨论了 CD 的光致发光机制,强调了其非晶结构,并将其与石墨烯量子点进行了比较。论文深入探讨了光盘在人工光合作用中的应用,通过改善光合成过程来促进作物生长。光盘通过与植物叶片相互作用,提高了阳光和二氧化碳的吸收率,从而有可能大幅提高作物产量。本文探讨了人工光合作用中 CD 的优势,包括其在紫外线到近红外光谱范围内可修改的吸收特性。论文承认了光盘生产中的挑战,如尺寸控制和聚集,同时强调了它们在传感、生物成像、能源设备和催化等各个领域的潜力。光盘独特的光学特性和广泛的应用表明,这些纳米结构在众多科学和技术领域前景广阔。
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Photoluminescent carbon nanodots for artificial photosynthesis
The emerging field of carbon dots (CDs), a type of carbon nanostructure that has gained significant attention due to its unique properties and potential applications. CDs possess remarkable attributes, including photoluminescence, electrochemical potential, compatibility with living organisms, solubility in water, chemical stability, and versatile surface properties. The chemical structure, particle size, and surface functionalities of CDs all have an impact on their photoluminescent properties, which are the focus of this review. The photoluminescence mechanism in CDs is discussed, highlighting their amorphous structure, and comparing them to graphene quantum dots. The paper delves into the application of CDs in artificial photosynthesis, which enhances crop growth by improving the photo-synthesis process. CDs increase sunlight and carbon dioxide absorption rates by interacting with plant leaves, potentially leading to substantial crop yield improvements. The advantages of CDs in artificial photosynthesis are explored, including their modifiable absorption characteristics across the ultraviolet to near-infrared spectrum. The paper acknowledges challenges in CD production, such as size control and aggregation, while emphasizing their potential in various fields, including sensing, bioimaging, energy devices, and catalysis. CDs' unique optical properties and versatile applications suggest a promising future for these nanostructures in numerous scientific and technological domains.
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