紫外纳米压印光刻--涂层技术对图案质量的影响

Johanna Rimböck, P. Schuster, Lisa Vsetecka, Christine Thanner
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摘要

在这项工作中,对三种不同的涂层技术进行了比较,并研究了它们在紫外纳米压印光刻(UV-NIL)中的适用性。由于 UV-NIL 被认为是一种适用于各种新兴应用的批量制造生产解决方案,因此必须考虑到环境方面的问题,如操作能耗、材料消耗以及废物管理。本文使用旋涂、喷涂和喷墨涂层分别对高折射率树脂(n = 1.9)和无填料树脂(n = 1.5)进行涂层。使用可变角度光谱椭偏仪 (VASE) 分析不同工艺参数对树脂厚度的影响,并比较每种涂层技术所获得的折射率。最后,通过在树脂层上压印不同的测试结构,研究了不同涂层方法对 UV-NIL 的适用性。对于最终压印,使用原子力显微镜评估了 25 次压印的分辨率、表面粗糙度和图案保真度。最后,对每种涂覆方法的树脂消耗量和工艺时间进行了比较。
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UV Nanoimprint Lithography—Impact of Coating Techniques on Pattern Quality
In this work, three different coating techniques are compared and their applicability for ultraviolet nanoimprint lithography (UV-NIL) is investigated. As UV-NIL is considered a suitable volume manufacturing production solution for various emerging applications, it is mandatory to consider environmental aspects such as operational energy use and material consumption as well as waste management. In this paper, spin coating, spray coating, and inkjet coating are used to coat both a high refractive index resin (n = 1.9) and a filler-free resin (n = 1.5), respectively. Variable Angle Spectroscopy Ellipsometry (VASE) was used to analyze the influence of different process parameters on the resin thickness as well as to compare the refractive index achieved from each coating technology. Finally, the applicability of the different coating methods for UV-NIL was investigated by imprinting the resin layers with different test structures. For the final imprints, the resolution, the surface roughness, and the pattern fidelity over 25 imprints was assessed using AFM. Finally, a comparison of the resin consumption and the process time was performed for each coating method.
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