合成氢氧化镁粉和干粉,用于扑灭石油火灾

IF 1.3 Q3 CHEMISTRY, MULTIDISCIPLINARY Vietnam Journal of Chemistry Pub Date : 2024-03-14 DOI:10.1002/vjch.202300279
Giang H. Le, Duong A. Thanh, Pham T. H. My, Trang T. T. Pham, Trang T. T. Quan, Quan Minh Nguyen, Quốc Anh Ngô
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引用次数: 0

摘要

灭火剂是灭火的一个重要因素。本研究合成了一种新型复合粉末(CSPMS),用于扑灭石油产品引起的火灾。二氧化硅纳米粒子、Mg(OH)2 纳米粒子和 NH4H2PO4/ 壳聚糖(CSP)纳米复合材料结合生成了 CSPMS 粉末。利用 XRD、SEM、FTIR 等方法对材料的结构和形态进行了表征。结果表明,在壳聚糖表面合成的 Mg(OH)2 纳米粒子大小为 20 至 30 nm,NH4H2PO4 纳米粒子大小为 800 至 900 nm。CSPMS 材料的粒径范围为 2 至 3 µm,表面均匀分布着 SiO2 纳米粒子(50-100 nm)和 Mg(OH)2 纳米粒子。这些粉末材料被用于扑灭汽油和石油火灾。CSPMS 样品的灭火时间和粉末消耗量(分别为 5.8 秒和 12.2 克)最佳,CO 排放量低于阈值 400 ppm。小规模灭火试验表明,与商用灭火粉末相比,CSPMS 粉末具有更好的灭火能力、冷却时间和 CO 气体吸附能力。
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Synthesis of magnesium hydroxide powder and dry powders for application in extinguishing petroleum fires
Fire extinguishing agents are an important factor in the fight against fires. In this study, a new composite powder (CSPMS) was synthesized and used to extinguish fires caused by petroleum products. SiO2 nanoparticles, Mg(OH)2 nanoparticles, and nanocomposites of NH4H2PO4/chitosan (CSP) were combined to generate CSPMS powder. The structure and morphology of the material were characterized using methods such as XRD, SEM, FTIR, etc. The results showed that the synthesized Mg(OH)2 nanoparticle size ranged from 20 to 30 nm, and the NH4H2PO4 nanoparticle size ranged from 800 to 900 nm on the chitosan surface. The CSPMS material had particle sizes ranging from 2 to 3 µm, with a uniform distribution of SiO2 nanoparticles (50–100 nm) and Mg(OH)2 nanoparticles on the surface. The powdered materials were applied to extinguish gasoline and oil fires. CSPMS sample demonstrated the best fire extinguishing time and powder consumption (5.8 s and 12.2 g, respectively) and CO emission below the threshold of 400 ppm. Small‐scale fire extinguishing tests showed that CSPMS powder had better fire extinguishing capability, cooling time, and CO gas adsorption ability compared to commercial fire extinguishing powder.
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来源期刊
Vietnam Journal of Chemistry
Vietnam Journal of Chemistry CHEMISTRY, MULTIDISCIPLINARY-
CiteScore
1.70
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