{"title":"混凝土在浸出和应力双重作用下的抗氯化物渗透能力","authors":"Shaowei Wang, Wenlong Gao, Yanyu Xiao, Jiawen Wu, Qun Xia","doi":"10.1680/jadcr.23.00227","DOIUrl":null,"url":null,"abstract":"Chloride penetration is one of the main causes for the failure of reinforced concrete structures, especially in undersea tunnels, which is also accompanied by stress and seepage water-induced calcium leaching. In this paper, the chloride penetration resistances of concrete under the single and dual effects of stress and calcium leaching were investigated, and the microscopic mechanism was explained by Scanning Electron Microscopy (SEM) and X-ray diffraction analysis (XRD). The results show that the chloride diffusion depth and chloride content linearly increase with the stress level in the tensile zone, while linearly decrease in the compressive zone, and the change is more obvious in the tensile zone. At stress levels of 15%, 30%, and 45%, the diffusion depth in the tensile zone increases by 11.4%, 36.6%, and 43.5%, respectively, and the increased ratios of chloride content are 1.2%, 11.2%, and 19.4%. There is no significant synergistic effect between stress and calcium leaching on chloride diffusion depth, but it is obvious on chloride content, especially when the tensile stress level is below 15% and the compressive stress level is above 30%, for which the differences caused by considering the synergistic effect or not are approximately 6% and 15%, respectively.","PeriodicalId":1,"journal":{"name":"Accounts of Chemical Research","volume":null,"pages":null},"PeriodicalIF":16.4000,"publicationDate":"2024-03-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Chloride penetration resistance of concrete under dual effects of leaching and stress\",\"authors\":\"Shaowei Wang, Wenlong Gao, Yanyu Xiao, Jiawen Wu, Qun Xia\",\"doi\":\"10.1680/jadcr.23.00227\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Chloride penetration is one of the main causes for the failure of reinforced concrete structures, especially in undersea tunnels, which is also accompanied by stress and seepage water-induced calcium leaching. In this paper, the chloride penetration resistances of concrete under the single and dual effects of stress and calcium leaching were investigated, and the microscopic mechanism was explained by Scanning Electron Microscopy (SEM) and X-ray diffraction analysis (XRD). The results show that the chloride diffusion depth and chloride content linearly increase with the stress level in the tensile zone, while linearly decrease in the compressive zone, and the change is more obvious in the tensile zone. At stress levels of 15%, 30%, and 45%, the diffusion depth in the tensile zone increases by 11.4%, 36.6%, and 43.5%, respectively, and the increased ratios of chloride content are 1.2%, 11.2%, and 19.4%. There is no significant synergistic effect between stress and calcium leaching on chloride diffusion depth, but it is obvious on chloride content, especially when the tensile stress level is below 15% and the compressive stress level is above 30%, for which the differences caused by considering the synergistic effect or not are approximately 6% and 15%, respectively.\",\"PeriodicalId\":1,\"journal\":{\"name\":\"Accounts of Chemical Research\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":16.4000,\"publicationDate\":\"2024-03-11\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Accounts of Chemical Research\",\"FirstCategoryId\":\"5\",\"ListUrlMain\":\"https://doi.org/10.1680/jadcr.23.00227\",\"RegionNum\":1,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Accounts of Chemical Research","FirstCategoryId":"5","ListUrlMain":"https://doi.org/10.1680/jadcr.23.00227","RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
Chloride penetration resistance of concrete under dual effects of leaching and stress
Chloride penetration is one of the main causes for the failure of reinforced concrete structures, especially in undersea tunnels, which is also accompanied by stress and seepage water-induced calcium leaching. In this paper, the chloride penetration resistances of concrete under the single and dual effects of stress and calcium leaching were investigated, and the microscopic mechanism was explained by Scanning Electron Microscopy (SEM) and X-ray diffraction analysis (XRD). The results show that the chloride diffusion depth and chloride content linearly increase with the stress level in the tensile zone, while linearly decrease in the compressive zone, and the change is more obvious in the tensile zone. At stress levels of 15%, 30%, and 45%, the diffusion depth in the tensile zone increases by 11.4%, 36.6%, and 43.5%, respectively, and the increased ratios of chloride content are 1.2%, 11.2%, and 19.4%. There is no significant synergistic effect between stress and calcium leaching on chloride diffusion depth, but it is obvious on chloride content, especially when the tensile stress level is below 15% and the compressive stress level is above 30%, for which the differences caused by considering the synergistic effect or not are approximately 6% and 15%, respectively.
期刊介绍:
Accounts of Chemical Research presents short, concise and critical articles offering easy-to-read overviews of basic research and applications in all areas of chemistry and biochemistry. These short reviews focus on research from the author’s own laboratory and are designed to teach the reader about a research project. In addition, Accounts of Chemical Research publishes commentaries that give an informed opinion on a current research problem. Special Issues online are devoted to a single topic of unusual activity and significance.
Accounts of Chemical Research replaces the traditional article abstract with an article "Conspectus." These entries synopsize the research affording the reader a closer look at the content and significance of an article. Through this provision of a more detailed description of the article contents, the Conspectus enhances the article's discoverability by search engines and the exposure for the research.