混凝土在浸出和应力双重作用下的抗氯化物渗透能力

IF 16.4 1区 化学 Q1 CHEMISTRY, MULTIDISCIPLINARY Accounts of Chemical Research Pub Date : 2024-03-11 DOI:10.1680/jadcr.23.00227
Shaowei Wang, Wenlong Gao, Yanyu Xiao, Jiawen Wu, Qun Xia
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引用次数: 0

摘要

氯化物渗透是钢筋混凝土结构失效的主要原因之一,尤其是在海底隧道中,同时还伴随着应力和渗水引起的钙浸出。本文研究了混凝土在应力和钙浸出单一效应和双重效应下的抗氯化物渗透性能,并通过扫描电子显微镜(SEM)和 X 射线衍射分析(XRD)解释了其微观机理。结果表明,在拉伸区,氯化物扩散深度和氯化物含量随应力水平的增加呈线性增加,而在压缩区则呈线性减少,且拉伸区的变化更为明显。当应力水平为 15%、30% 和 45% 时,拉伸区的扩散深度分别增加了 11.4%、36.6% 和 43.5%,氯化物含量的增加比率分别为 1.2%、11.2% 和 19.4%。应力和钙浸出对氯化物扩散深度没有明显的协同效应,但对氯化物含量有明显的协同效应,特别是当拉伸应力水平低于 15%、压缩应力水平高于 30%时,考虑协同效应与否造成的差异分别约为 6%和 15%。
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Chloride penetration resistance of concrete under dual effects of leaching and stress
Chloride penetration is one of the main causes for the failure of reinforced concrete structures, especially in undersea tunnels, which is also accompanied by stress and seepage water-induced calcium leaching. In this paper, the chloride penetration resistances of concrete under the single and dual effects of stress and calcium leaching were investigated, and the microscopic mechanism was explained by Scanning Electron Microscopy (SEM) and X-ray diffraction analysis (XRD). The results show that the chloride diffusion depth and chloride content linearly increase with the stress level in the tensile zone, while linearly decrease in the compressive zone, and the change is more obvious in the tensile zone. At stress levels of 15%, 30%, and 45%, the diffusion depth in the tensile zone increases by 11.4%, 36.6%, and 43.5%, respectively, and the increased ratios of chloride content are 1.2%, 11.2%, and 19.4%. There is no significant synergistic effect between stress and calcium leaching on chloride diffusion depth, but it is obvious on chloride content, especially when the tensile stress level is below 15% and the compressive stress level is above 30%, for which the differences caused by considering the synergistic effect or not are approximately 6% and 15%, respectively.
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来源期刊
Accounts of Chemical Research
Accounts of Chemical Research 化学-化学综合
CiteScore
31.40
自引率
1.10%
发文量
312
审稿时长
2 months
期刊介绍: Accounts of Chemical Research presents short, concise and critical articles offering easy-to-read overviews of basic research and applications in all areas of chemistry and biochemistry. These short reviews focus on research from the author’s own laboratory and are designed to teach the reader about a research project. In addition, Accounts of Chemical Research publishes commentaries that give an informed opinion on a current research problem. Special Issues online are devoted to a single topic of unusual activity and significance. Accounts of Chemical Research replaces the traditional article abstract with an article "Conspectus." These entries synopsize the research affording the reader a closer look at the content and significance of an article. Through this provision of a more detailed description of the article contents, the Conspectus enhances the article's discoverability by search engines and the exposure for the research.
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