磷酸盐中的金:积累形式和实际意义

A. F. Georgievskiy, V. Bugina
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摘要

研究课题。现代(海洋)和古代工业类型磷酸盐矿的含金潜力,包括闪锌矿、微粒状矿、粒状矿、结核矿、贝壳矿和岩溶矿。目的评估磷酸盐矿积聚金达到工业浓度的能力。近年来,由于高精度物质研究方法的出现,地质学界一直在积极讨论这一问题。方法。俄罗斯和外国出版物、未发表的地质数据以及作者在研究磷酸盐岩的 30 年间收集的数据。结果和讨论。在该断面上,共发现了 14 组岩石,分别代表 6 种岩性类型的次生白云岩。这些岩石在断面上的分布以及特征性动物遗骸的存在,使我们有可能在断面上确定三个成员,它们分别与一般地层尺度的卡蒂期、希尔南期和鲁丹期相关联。结论黑色页岩盆地以及含青金石-砂沉积物的陆架浅水中可能存在磷酸盐和金的共同积累条件。然而,由于金和磷酸盐的自然特征存在显著差异,它们的产业集群是相互独立形成的。黑页岩地层的金矿床矿石中磷的累积量微乎其微,而含磷盆地的工业磷矿床中磷的浓度也很低,这都证明了这一点。对于金而言,磷酸盐岩只是暂时的收集器,其生产率取决于许多因素的组合,这些因素经常是随机的,而且略有关联。
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Gold in phosphorites: Accumulation forms and practical significance
Research subject. The gold-bearing potential of modern (oceanic) and ancient industrial types of phosphorite ores, including aphanitic, microgranular, granular, nodular, shell and karst. Aim. To assess the ability of phosphorites to accumulate gold to industrial concentrations. This issue has been actively discussed in the geological community in recent years due to the advent of high-precision methods for studying matter. Methods. Russian and foreign publications, unpublished geological data, as well as the authors’ data collected over a 30-year period of studying phosphorites. Results and discussion. In the section, 14 packs of rocks were identified, which are represented by 6 lithological types of secondary dolomites. Their distribution along the section, along with the presence of characteristic faunal remains, made it possible to establish three members in the section, which can be correlated with the Katian, Hirnantian, and Ruddanian stages of the General Stratigraphic Scale. Conclusion. Conditions for the possible joint accumulation of phosphates and gold are manifested in black shale basins, as well as in shelf shallow waters with glauconite-sand sediments. However, due to significant differences in the natural features of gold and phosphates, their industrial clusters are formed separately from each other. This is evidenced by the insignificant accumulation of phosphorus in the ores of gold deposits of black shale formations,as well as its low-quality concentrations in industrial phosphorite beds of phosphorite-bearing basins. For gold, phosphorites are only temporary collectors, the productivity of which depends on the combination of many, frequently random and slightly related factors.
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