将还原氧化石墨烯裁剪成纳米纤维结构:制造、表征和功能见解

Jawaria Rehman, Nadia Anwar, Muqarrab Ahmed, Shaheen Irfan, Ghazi Aman Nowsherwan, Abdul Waheed Anwar, Nazia Iram, Javeria Arshad, Nosheen Mushahid, Ayesha Saleem
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引用次数: 0

摘要

电纺丝工艺可从聚合物溶液中生产出纳米纤维,使其适用于各种应用,如传感器、电子设备、导电材料和高温环境下的先进复合材料。在这项研究中,聚苯胺(PANI)掺杂了樟脑磺酸(HCSA)。HCSA 掺杂剂用于改变聚苯胺的电气和结构特性。引入还原氧化石墨烯作为纳米填料,以增强聚合物的电气性能。分别电纺掺杂了 HCSA 的 PANI 和掺杂了 HCSA 的 PANI 与 rGO 纳米纤维,以生成单独的纳米纤维。傅立叶变换红外光谱法用于研究纳米纤维中的化学成分和官能团。场发射扫描电子显微镜用于研究纳米纤维的形态、结构和表面特征。热重分析用于评估纳米纤维的热稳定性和 rGO 的大致含量。这些结果表明,添加还原氧化石墨烯(rGO)可提高纳米纤维的导电性和热稳定性。
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Tailoring reduced graphene oxide into nanofibrous architectures: fabrication, characterization, and functional insights
The electrospinning process allows the production of nanofibers from polymer solutions, making them suitable for various applications such as sensors, electronic devices, conductive materials, and advanced composites for high-temperature environments. In this research, polyaniline (PANI) was doped with camphor sulfonic camphor sulfonic acid (HCSA). HCSA dopant is used to modify the electrical and structural properties of polyaniline. To introduce reduced graphene oxide as a nanofiller to enhance the electrical properties of the polymer. Both the HCSA-doped PANI and HCSA-doped PANI with rGO nanofibers were electro-spun separately to create individual nanofibers. Fourier-transform infrared spectroscopy was used to investigate the chemical composition and functional groups present in the nanofibers. Field emission scanning electron microscopy was employed to study the nanofibers’ morphology, structure, and surface characteristics. Thermogravimetric analysis was used to assess the thermal stability of the nanofibers and to approximate the content of rGO. These results indicate that the addition of reduced graphene oxide (rGO) led to improvements in the nanofibers’ electrical conductivity and thermal stability.
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