Zijun Yi, Xin Li, Yuchen Xiong, Guibin Shen, Wenguang Zhang, Yihuai Huang, Qinghui Jiang, Xin Ren Ng, Yubo Luo, Jianghui Zheng, Wei Lin Leong, Fan Fu, Tongle Bu, Junyou Yang
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引用次数: 0
摘要
由于自组装单层具有操纵化学和物理界面特性的独特能力和多功能性,倒置包晶体太阳能电池(PSCs)中使用的自组装单层在单结和串联配置的器件效率和稳定性方面取得了突破性进展。在这方面,我们全面综述了最近有关反相包晶石单结和串联太阳能电池中 SAM 的研究进展,并强调了 SAM 应用中的当前挑战和未来发展前景。我们深入研究了各种 SAM 在能级调节、界面修饰、缺陷钝化和电荷传输中的机理作用。通过了解如何对界面分子相互作用进行微调,以减轻倒置 PSC 中的电荷重组损耗,从而实现这一目标。通过本综述,我们希望为进一步研究和利用倒置包晶单结和串联太阳能电池中的 SAM 提供有价值的见解和参考。
Self-assembled monolayers (SAMs) in inverted perovskite solar cells and their tandem photovoltaics application
Self-assembled monolayers (SAMs) employed in inverted perovskite solar cells (PSCs) have achieved groundbreaking progress in device efficiency and stability for both single-junction and tandem configurations, owing to their distinctive and versatile ability to manipulate chemical and physical interface properties. In this regard, we present a comprehensive review of recent research advancements concerning SAMs in inverted perovskite single-junction and tandem solar cells, where the prevailing challenges and future development prospects in the applications of SAMs are emphasized. We thoroughly examine the mechanistic roles of diverse SAMs in energy-level regulation, interface modification, defect passivation, and charge transportation. This is achieved by understanding how interfacial molecular interactions can be finely tuned to mitigate charge recombination losses in inverted PSCs. Through this comprehensive review, we aim to provide valuable insights and references for further investigation and utilization of SAMs in inverted perovskite single-junction and tandem solar cells.