H2O、D2O 和惰性物质相图的比较

Pub Date : 2024-03-26 DOI:10.1063/10.0024971
L. A. Bulavin, Ye. G. Rudnikov, N. I. Lebovka
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引用次数: 0

摘要

比较了轻 H2O、重 D2O 水和惰性物质(Ne、Ar、Kr 和 Xe)的相图。提出了一种选择熵和内能起点的方法。这种方法可以利用热量变量测试相应状态的原理。在给定的温度、压力和化学势坐标下,水的同素异形体形成一组物质,并具有相似的相图。相同坐标下的惰性物质组成另一组物质,具有相似的相图。具有重要德布尔量子参数的惰性 Ne 的相图与其他惰性物质的相图有一定程度的差异。
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Comparison of phase diagrams of H2O, D2O, and inert substances
The phase diagrams for the light H2O, heavy D2O water, and inert substances (Ne, Ar, Kr, and Xe) have been compared. A method of choosing the starting point for entropy and internal energy was proposed. It allowed testing the principle of corresponding states using caloric variables. In the given coordinates of temperature, pressure, and chemical potential, the water isotopologues form one group of substances and have similar phase diagrams. The inert substances in the same coordinates form another group of substances with similar phase diagrams. The phase diagrams for inert Ne with significant de Boer quantum parameters differ to a certain extent from the phase diagrams of other inert substances.
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