MXene 作为高性能锂离子电池的理想正极材料:全面回顾

Nanomaterials Pub Date : 2024-03-31 DOI:10.3390/nano14070616
Mohammad Nezam Uddin Chy, Md. Arafat Rahman, Jin-Hyuk Kim, Nirjhor Barua, Wasif Abu Dujana
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引用次数: 0

摘要

由于制备方法的多样性以及新成员的不断发现,MXene 材料已开始广泛应用于超级电容器和电池等各种储能技术中。锂离子电池(LIB)对优秀负极材料的基本要求是安全性高、在锂化/去锂化过程中体积膨胀最小、高循环稳定性和高 Li+ 储存能力。然而,大多数用于锂离子电池的负极材料,如石墨、二氧化锡、硅、铝和 Li4Ti5O12,都至少存在一个问题。因此,创造新型负极材料仍然十分困难。迄今为止,已有一些 MXenes 材料因其独特的活性电压窗口、大功率能力和较长的循环寿命而被实验研究用作 LIB 的阳极。本综述论文旨在概述作为锂离子电池阳极材料的 MXenes 的合成和表征特性,包括其放电/充电容量、速率性能和循环能力。此外,本文还概述了这些材料作为阳极的潜在发展前景。
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MXene as Promising Anode Material for High-Performance Lithium-Ion Batteries: A Comprehensive Review
Broad adoption has already been started of MXene materials in various energy storage technologies, such as super-capacitors and batteries, due to the increasing versatility of the preparation methods, as well as the ongoing discovery of new members. The essential requirements for an excellent anode material for lithium-ion batteries (LIBs) are high safety, minimal volume expansion during the lithiation/de-lithiation process, high cyclic stability, and high Li+ storage capability. However, most of the anode materials for LIBs, such as graphite, SnO2, Si, Al, and Li4Ti5O12, have at least one issue. Hence, creating novel anode materials continues to be difficult. To date, a few MXenes have been investigated experimentally as anodes of LIBs due to their distinct active voltage windows, large power capabilities, and longer cyclic life. The objective of this review paper is to provide an overview of the synthesis and characterization characteristics of the MXenes as anode materials of LIBs, including their discharge/charge capacity, rate performance, and cycle ability. In addition, a summary of the potential outlook for developments of these materials as anodes is provided.
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