Igor Ferraz Torres, Sandro Marden Torres, Tibério Andrade
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From risk study to field evidence: an unprecedented and isolated case of DEF in Brazil
This paper presents the first case ever reported in Brazil where delayed ettringite formation (DEF) has been confirmed as the sole cause of deterioration in field concrete. Still under construction and with less than 2 years of age, numerous cracks were observed in the foundation structures of a building located in Recife, a city known for its history of alkali-aggregate reaction (AAR) cases. In addition to the field survey of cracks, microstructural analyses, residual expansion, compressive strength, review of structural design, the determination of the sulfates content in the groundwater and simplified thermal analysis were carried out. Results confirmed that the DEF was the isolated cause of the damages present in those cast-in-place concrete structures, with no evidence of AAR or any other deterioration process. This work corroborates studies previously published on the high risk of the occurrence of DEF in the region, demonstrating the urgent need for a preventive technical standard in the country, considering the chemical composition of cements and mainly prior thermal analyzes to adopt possible preventive measures to limit the maximum internal temperature of the concrete.
期刊介绍:
Accounts of Chemical Research presents short, concise and critical articles offering easy-to-read overviews of basic research and applications in all areas of chemistry and biochemistry. These short reviews focus on research from the author’s own laboratory and are designed to teach the reader about a research project. In addition, Accounts of Chemical Research publishes commentaries that give an informed opinion on a current research problem. Special Issues online are devoted to a single topic of unusual activity and significance.
Accounts of Chemical Research replaces the traditional article abstract with an article "Conspectus." These entries synopsize the research affording the reader a closer look at the content and significance of an article. Through this provision of a more detailed description of the article contents, the Conspectus enhances the article's discoverability by search engines and the exposure for the research.