从风险研究到实地证据:巴西前所未有的 DEF 个案

IF 17.7 1区 化学 Q1 CHEMISTRY, MULTIDISCIPLINARY Accounts of Chemical Research Pub Date : 2024-03-29 DOI:10.1680/jmacr.23.00272
Igor Ferraz Torres, Sandro Marden Torres, Tibério Andrade
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引用次数: 0

摘要

本文介绍了巴西有史以来第一例被证实为导致现场混凝土老化的唯一原因的延迟陶粒岩形成(DEF)案例。位于累西腓(Recife)的一栋建筑仍在建设中,龄期不足两年,在其地基结构中发现了大量裂缝,而累西腓是一座以碱骨料反应(AAR)案例而闻名的城市。除了对裂缝进行实地调查外,还进行了微观结构分析、残余膨胀、抗压强度、结构设计审查、地下水硫酸盐含量测定和简化热分析。结果证实,DEF 是造成这些现浇混凝土结构损坏的唯一原因,没有证据表明存在 AAR 或任何其他劣化过程。这项工作证实了之前发表的关于该地区发生 DEF 的高风险的研究,表明该国迫切需要制定预防性技术标准,考虑水泥的化学成分,主要是事先进行热分析,以采取可能的预防措施,限制混凝土的最高内部温度。
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From risk study to field evidence: an unprecedented and isolated case of DEF in Brazil
This paper presents the first case ever reported in Brazil where delayed ettringite formation (DEF) has been confirmed as the sole cause of deterioration in field concrete. Still under construction and with less than 2 years of age, numerous cracks were observed in the foundation structures of a building located in Recife, a city known for its history of alkali-aggregate reaction (AAR) cases. In addition to the field survey of cracks, microstructural analyses, residual expansion, compressive strength, review of structural design, the determination of the sulfates content in the groundwater and simplified thermal analysis were carried out. Results confirmed that the DEF was the isolated cause of the damages present in those cast-in-place concrete structures, with no evidence of AAR or any other deterioration process. This work corroborates studies previously published on the high risk of the occurrence of DEF in the region, demonstrating the urgent need for a preventive technical standard in the country, considering the chemical composition of cements and mainly prior thermal analyzes to adopt possible preventive measures to limit the maximum internal temperature of the concrete.
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来源期刊
Accounts of Chemical Research
Accounts of Chemical Research 化学-化学综合
CiteScore
31.40
自引率
1.10%
发文量
312
审稿时长
2 months
期刊介绍: Accounts of Chemical Research presents short, concise and critical articles offering easy-to-read overviews of basic research and applications in all areas of chemistry and biochemistry. These short reviews focus on research from the author’s own laboratory and are designed to teach the reader about a research project. In addition, Accounts of Chemical Research publishes commentaries that give an informed opinion on a current research problem. Special Issues online are devoted to a single topic of unusual activity and significance. Accounts of Chemical Research replaces the traditional article abstract with an article "Conspectus." These entries synopsize the research affording the reader a closer look at the content and significance of an article. Through this provision of a more detailed description of the article contents, the Conspectus enhances the article's discoverability by search engines and the exposure for the research.
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