索马里埃尔阿里铁陨石中的三种新的铁磷酸盐矿物:埃尔阿里铁陨石,Fe2+8Fe3+ (PO4)O8;埃尔金斯坦顿铁陨石,Fe4(PO4)2O;以及奥尔森铁陨石,KFe4(PO4)3

IF 2.7 3区 地球科学 Q2 GEOCHEMISTRY & GEOPHYSICS American Mineralogist Pub Date : 2024-03-28 DOI:10.2138/am-2023-9225
C. D. Herd, Chi Ma, A. Locock, Radhika Saini, E. Walton
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引用次数: 0

摘要

对埃尔阿里 IAB 铁陨石(索马里)进行的岩石学调查发现了三种新矿物:埃拉利石(Fe2+8Fe3+ (PO4)O8,IMA 2022-087)、埃尔金斯坦顿石(Fe4(PO4)2O,IMA 2022-088)和奥尔森石(KFe4(PO4)3,IMA 2022-100)。埃尔阿里陨石原位于北纬 4° 17′ 17″,东经 44° 53′ 54″,埃尔阿里陨石的名称是对埃尔阿里陨石中出现的这种矿物的认可。埃尔金斯坦顿石以行星科学家、亚利桑那州立大学地球与太空探索学院教授琳达-埃尔金斯坦顿(Linda (Lindy) Elkins-Tanton,生于 1965 年)的名字命名。奥尔森石是为了纪念芝加哥菲尔德自然历史博物馆矿物学和陨石馆前馆长爱德华-J-奥尔森(Edward J. Olsen,1927-2020 年)(1960-1991 年)。这些新矿物及其名称已获得国际矿物学协会新矿物、命名和分类委员会(Commission on New Minerals, Nomenclature and Classification of the International Mineralogical Association)的批准。elaliite、elkinstantonite 和 olsenite 的主模式标本由存放在阿尔伯塔大学陨石收藏馆的编号为 MET11814/2-1/EP1 的抛光块状底座组成。埃拉利石、埃尔金斯坦顿石和奥尔森特石与乌斯托石、特罗利石、弧闪石和含钙质的石榴石一起出现在构成埃尔阿里样本主体的铁镍金属(卡马奇石,镍含量为 9.4 wt%)的包裹体中。通过电子探针显微分析法确定的埃利石、埃金石和奥尔森石的经验公式为(Fe2+7.943Fe3+1.020Cr0.010Ni0.006Ca0.004Mn0.004)Σ8.987(P0.932Si0.077S0.005)Σ1.014O12, (Fe2+3.947Mn0.016Ni0.003Ca0.001Cr0.001)Σ3.968(P1.986Si0.014S0.013)Σ2.013O9, and (K0.820Na0.135Ca0.004)Σ0.959(Fe3.829Mn0.050)Σ3.879(P2.972S0.058Si0.017)Σ3.047O12.电子反向散射衍射被用来确认这三种新矿物的晶体结构。此外,还展示了这三种矿物的拉曼光谱。
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Three new iron-phosphate minerals from the El Ali iron meteorite, Somalia: Elaliite, Fe2+8Fe3+ (PO4)O8; elkinstantonite, Fe4(PO4)2O; and olsenite, KFe4(PO4)3
Petrologic investigation of the El Ali IAB iron meteorite (Somalia) revealed three new minerals: elaliite (Fe2+8Fe3+ (PO4)O8, IMA 2022-087), elkinstantonite(Fe4(PO4)2O, IMA 2022-088), and olsenite (KFe4(PO4)3, IMA 2022-100). The name elaliite recognizes the occurrence of this mineral within the El Ali meteorite, originally located at 4° 17′ 17″N, 44° 53′ 54″E. Elkinstantonite is named after Linda (Lindy) Elkins-Tanton (b. 1965), a planetary scientist and professor in the School of Earth and Space Exploration at Arizona State University. The name olsenite is in honor of Edward J. Olsen (1927-2020), the former Curator of Mineralogy and Meteorites at the Field Museum of Natural History in Chicago (1960-1991). The new minerals and their names have been approved by the Commission on New Minerals, Nomenclature and Classification of the International Mineralogical Association. The holotype specimens of elaliite, elkinstantonite and olsenite consist of the polished block mount with accession number MET11814/2-1/EP1 deposited in the University of Alberta Meteorite Collection. Elaliite, elkinstantonite and olsenite occur along with wustite, troilite, sarcopside and Ca-bearing graftonite within inclusions in the iron-nickel metal (kamacite, 9.4 wt% Ni) that makes up the bulk of the El Ali sample. The empirical formulas determined by electron probe microanalysis for elaliite, elkinstantonite, and olsenite are: (Fe2+7.943Fe3+1.020Cr0.010Ni0.006Ca0.004Mn0.004)Σ8.987(P0.932Si0.077S0.005)Σ1.014O12, (Fe2+3.947Mn0.016Ni0.003Ca0.001Cr0.001)Σ3.968(P1.986Si0.014S0.013)Σ2.013O9, and (K0.820Na0.135Ca0.004)Σ0.959(Fe3.829Mn0.050)Σ3.879(P2.972S0.058Si0.017)Σ3.047O12. Electron backscatter diffraction was used to confirm the crystal structures of the three new minerals. Raman spectra for all three minerals are also presented.
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来源期刊
American Mineralogist
American Mineralogist 地学-地球化学与地球物理
CiteScore
5.20
自引率
9.70%
发文量
276
审稿时长
1 months
期刊介绍: American Mineralogist: Journal of Earth and Planetary Materials (Am Min), is the flagship journal of the Mineralogical Society of America (MSA), continuously published since 1916. Am Min is home to some of the most important advances in the Earth Sciences. Our mission is a continuance of this heritage: to provide readers with reports on original scientific research, both fundamental and applied, with far reaching implications and far ranging appeal. Topics of interest cover all aspects of planetary evolution, and biological and atmospheric processes mediated by solid-state phenomena. These include, but are not limited to, mineralogy and crystallography, high- and low-temperature geochemistry, petrology, geofluids, bio-geochemistry, bio-mineralogy, synthetic materials of relevance to the Earth and planetary sciences, and breakthroughs in analytical methods of any of the aforementioned.
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