C. D. Herd, Chi Ma, A. Locock, Radhika Saini, E. Walton
{"title":"索马里埃尔阿里铁陨石中的三种新的铁磷酸盐矿物:埃尔阿里铁陨石,Fe2+8Fe3+ (PO4)O8;埃尔金斯坦顿铁陨石,Fe4(PO4)2O;以及奥尔森铁陨石,KFe4(PO4)3","authors":"C. D. Herd, Chi Ma, A. Locock, Radhika Saini, E. Walton","doi":"10.2138/am-2023-9225","DOIUrl":null,"url":null,"abstract":"\n Petrologic investigation of the El Ali IAB iron meteorite (Somalia) revealed three new minerals: elaliite (Fe2+8Fe3+ (PO4)O8, IMA 2022-087), elkinstantonite(Fe4(PO4)2O, IMA 2022-088), and olsenite (KFe4(PO4)3, IMA 2022-100). The name elaliite recognizes the occurrence of this mineral within the El Ali meteorite, originally located at 4° 17′ 17″N, 44° 53′ 54″E. Elkinstantonite is named after Linda (Lindy) Elkins-Tanton (b. 1965), a planetary scientist and professor in the School of Earth and Space Exploration at Arizona State University. The name olsenite is in honor of Edward J. Olsen (1927-2020), the former Curator of Mineralogy and Meteorites at the Field Museum of Natural History in Chicago (1960-1991). The new minerals and their names have been approved by the Commission on New Minerals, Nomenclature and Classification of the International Mineralogical Association. The holotype specimens of elaliite, elkinstantonite and olsenite consist of the polished block mount with accession number MET11814/2-1/EP1 deposited in the University of Alberta Meteorite Collection. Elaliite, elkinstantonite and olsenite occur along with wustite, troilite, sarcopside and Ca-bearing graftonite within inclusions in the iron-nickel metal (kamacite, 9.4 wt% Ni) that makes up the bulk of the El Ali sample. The empirical formulas determined by electron probe microanalysis for elaliite, elkinstantonite, and olsenite are: (Fe2+7.943Fe3+1.020Cr0.010Ni0.006Ca0.004Mn0.004)Σ8.987(P0.932Si0.077S0.005)Σ1.014O12, (Fe2+3.947Mn0.016Ni0.003Ca0.001Cr0.001)Σ3.968(P1.986Si0.014S0.013)Σ2.013O9, and (K0.820Na0.135Ca0.004)Σ0.959(Fe3.829Mn0.050)Σ3.879(P2.972S0.058Si0.017)Σ3.047O12. Electron backscatter diffraction was used to confirm the crystal structures of the three new minerals. Raman spectra for all three minerals are also presented.","PeriodicalId":2,"journal":{"name":"ACS Applied Bio Materials","volume":"64 5","pages":""},"PeriodicalIF":4.7000,"publicationDate":"2024-03-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Three new iron-phosphate minerals from the El Ali iron meteorite, Somalia: Elaliite, Fe2+8Fe3+ (PO4)O8; elkinstantonite, Fe4(PO4)2O; and olsenite, KFe4(PO4)3\",\"authors\":\"C. D. Herd, Chi Ma, A. Locock, Radhika Saini, E. Walton\",\"doi\":\"10.2138/am-2023-9225\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"\\n Petrologic investigation of the El Ali IAB iron meteorite (Somalia) revealed three new minerals: elaliite (Fe2+8Fe3+ (PO4)O8, IMA 2022-087), elkinstantonite(Fe4(PO4)2O, IMA 2022-088), and olsenite (KFe4(PO4)3, IMA 2022-100). The name elaliite recognizes the occurrence of this mineral within the El Ali meteorite, originally located at 4° 17′ 17″N, 44° 53′ 54″E. Elkinstantonite is named after Linda (Lindy) Elkins-Tanton (b. 1965), a planetary scientist and professor in the School of Earth and Space Exploration at Arizona State University. The name olsenite is in honor of Edward J. Olsen (1927-2020), the former Curator of Mineralogy and Meteorites at the Field Museum of Natural History in Chicago (1960-1991). The new minerals and their names have been approved by the Commission on New Minerals, Nomenclature and Classification of the International Mineralogical Association. The holotype specimens of elaliite, elkinstantonite and olsenite consist of the polished block mount with accession number MET11814/2-1/EP1 deposited in the University of Alberta Meteorite Collection. Elaliite, elkinstantonite and olsenite occur along with wustite, troilite, sarcopside and Ca-bearing graftonite within inclusions in the iron-nickel metal (kamacite, 9.4 wt% Ni) that makes up the bulk of the El Ali sample. The empirical formulas determined by electron probe microanalysis for elaliite, elkinstantonite, and olsenite are: (Fe2+7.943Fe3+1.020Cr0.010Ni0.006Ca0.004Mn0.004)Σ8.987(P0.932Si0.077S0.005)Σ1.014O12, (Fe2+3.947Mn0.016Ni0.003Ca0.001Cr0.001)Σ3.968(P1.986Si0.014S0.013)Σ2.013O9, and (K0.820Na0.135Ca0.004)Σ0.959(Fe3.829Mn0.050)Σ3.879(P2.972S0.058Si0.017)Σ3.047O12. Electron backscatter diffraction was used to confirm the crystal structures of the three new minerals. 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引用次数: 0
摘要
对埃尔阿里 IAB 铁陨石(索马里)进行的岩石学调查发现了三种新矿物:埃拉利石(Fe2+8Fe3+ (PO4)O8,IMA 2022-087)、埃尔金斯坦顿石(Fe4(PO4)2O,IMA 2022-088)和奥尔森石(KFe4(PO4)3,IMA 2022-100)。埃尔阿里陨石原位于北纬 4° 17′ 17″,东经 44° 53′ 54″,埃尔阿里陨石的名称是对埃尔阿里陨石中出现的这种矿物的认可。埃尔金斯坦顿石以行星科学家、亚利桑那州立大学地球与太空探索学院教授琳达-埃尔金斯坦顿(Linda (Lindy) Elkins-Tanton,生于 1965 年)的名字命名。奥尔森石是为了纪念芝加哥菲尔德自然历史博物馆矿物学和陨石馆前馆长爱德华-J-奥尔森(Edward J. Olsen,1927-2020 年)(1960-1991 年)。这些新矿物及其名称已获得国际矿物学协会新矿物、命名和分类委员会(Commission on New Minerals, Nomenclature and Classification of the International Mineralogical Association)的批准。elaliite、elkinstantonite 和 olsenite 的主模式标本由存放在阿尔伯塔大学陨石收藏馆的编号为 MET11814/2-1/EP1 的抛光块状底座组成。埃拉利石、埃尔金斯坦顿石和奥尔森特石与乌斯托石、特罗利石、弧闪石和含钙质的石榴石一起出现在构成埃尔阿里样本主体的铁镍金属(卡马奇石,镍含量为 9.4 wt%)的包裹体中。通过电子探针显微分析法确定的埃利石、埃金石和奥尔森石的经验公式为(Fe2+7.943Fe3+1.020Cr0.010Ni0.006Ca0.004Mn0.004)Σ8.987(P0.932Si0.077S0.005)Σ1.014O12, (Fe2+3.947Mn0.016Ni0.003Ca0.001Cr0.001)Σ3.968(P1.986Si0.014S0.013)Σ2.013O9, and (K0.820Na0.135Ca0.004)Σ0.959(Fe3.829Mn0.050)Σ3.879(P2.972S0.058Si0.017)Σ3.047O12.电子反向散射衍射被用来确认这三种新矿物的晶体结构。此外,还展示了这三种矿物的拉曼光谱。
Three new iron-phosphate minerals from the El Ali iron meteorite, Somalia: Elaliite, Fe2+8Fe3+ (PO4)O8; elkinstantonite, Fe4(PO4)2O; and olsenite, KFe4(PO4)3
Petrologic investigation of the El Ali IAB iron meteorite (Somalia) revealed three new minerals: elaliite (Fe2+8Fe3+ (PO4)O8, IMA 2022-087), elkinstantonite(Fe4(PO4)2O, IMA 2022-088), and olsenite (KFe4(PO4)3, IMA 2022-100). The name elaliite recognizes the occurrence of this mineral within the El Ali meteorite, originally located at 4° 17′ 17″N, 44° 53′ 54″E. Elkinstantonite is named after Linda (Lindy) Elkins-Tanton (b. 1965), a planetary scientist and professor in the School of Earth and Space Exploration at Arizona State University. The name olsenite is in honor of Edward J. Olsen (1927-2020), the former Curator of Mineralogy and Meteorites at the Field Museum of Natural History in Chicago (1960-1991). The new minerals and their names have been approved by the Commission on New Minerals, Nomenclature and Classification of the International Mineralogical Association. The holotype specimens of elaliite, elkinstantonite and olsenite consist of the polished block mount with accession number MET11814/2-1/EP1 deposited in the University of Alberta Meteorite Collection. Elaliite, elkinstantonite and olsenite occur along with wustite, troilite, sarcopside and Ca-bearing graftonite within inclusions in the iron-nickel metal (kamacite, 9.4 wt% Ni) that makes up the bulk of the El Ali sample. The empirical formulas determined by electron probe microanalysis for elaliite, elkinstantonite, and olsenite are: (Fe2+7.943Fe3+1.020Cr0.010Ni0.006Ca0.004Mn0.004)Σ8.987(P0.932Si0.077S0.005)Σ1.014O12, (Fe2+3.947Mn0.016Ni0.003Ca0.001Cr0.001)Σ3.968(P1.986Si0.014S0.013)Σ2.013O9, and (K0.820Na0.135Ca0.004)Σ0.959(Fe3.829Mn0.050)Σ3.879(P2.972S0.058Si0.017)Σ3.047O12. Electron backscatter diffraction was used to confirm the crystal structures of the three new minerals. Raman spectra for all three minerals are also presented.
期刊介绍:
ACS Applied Bio Materials is an interdisciplinary journal publishing original research covering all aspects of biomaterials and biointerfaces including and beyond the traditional biosensing, biomedical and therapeutic applications.
The journal is devoted to reports of new and original experimental and theoretical research of an applied nature that integrates knowledge in the areas of materials, engineering, physics, bioscience, and chemistry into important bio applications. The journal is specifically interested in work that addresses the relationship between structure and function and assesses the stability and degradation of materials under relevant environmental and biological conditions.