水中水的 pKa 值:一个长期存在、令人厌倦但很快就会被遗忘的问题?

IF 1.1 4区 化学 Q3 CHEMISTRY, MULTIDISCIPLINARY Chimia Pub Date : 2024-03-27 DOI:10.2533/chimia.2024.167
Antonio Togni
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引用次数: 0

摘要

水和水中氢离子(质子)的 pKa 值分别为 14 和 0。然而,许多普通化学、有机化学以及无机化学教科书中却分别提供了 15.74 和-1.74 这两个错误的数值。本专栏简要介绍了这两对不同数值这一长期存在的问题,以及在普通化学教学中产生的后果,并希望这一问题能尽快得到解决。
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The pKa Values of Water in Water: A Long-Standing, Tiresome, yet Soon Forgotten Issue?
The pKa values of water and the hydrogen ion (proton) in water are 14 and 0, respectively. Yet, many textbooks of general, organic, and, to a lesser extent, inorganic chemistry provide the incorrect values 15.74 and -1.74, respectively. This column briefly introduces the long-standing issue of these two different pairs of values, the consequences it bears when teaching general chemistry, and expresses the hope that it may be solved soon.
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来源期刊
Chimia
Chimia 化学-化学综合
CiteScore
1.60
自引率
0.00%
发文量
144
审稿时长
2 months
期刊介绍: CHIMIA, a scientific journal for chemistry in the broadest sense covers the interests of a wide and diverse readership. Contributions from all fields of chemistry and related areas are considered for publication in the form of Review Articles and Notes. A characteristic feature of CHIMIA are the thematic issues, each devoted to an area of great current significance.
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