分子筛支撑催化剂在含氯挥发性有机化合物催化氧化中的研究进展

Chunyan Feng
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摘要

氯化挥发性有机化合物(CVOCs)来源广泛,是 PM2.5 和臭氧污染的常见前体物,对环境构成严重威胁,并对人类健康产生不利影响。催化降解是解决 CVOCs 污染的有效方法之一,具有操作温度低、含氯副产物少、降解效率高等优点。该技术的核心是设计和开发具有优异稳定性和催化性能的催化剂材料。目前,分子筛催化剂因其酸性和独特的孔结构而受到广泛关注。本文总结分析了贵金属、过渡金属氧化物和过氧化物等分子筛支撑催化剂的研究现状及其在 CVOCs 催化反应中的活性、酸性、稳定性和选择性,并展望了 CVOCs 分子筛支撑催化剂的未来发展方向。
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Research progress of molecular sieve supported catalysts in catalytic oxidation of chlorine-containing volatile organic compounds
Chlorinated Volatile Organic Compounds (CVOCs) come from a wide range of sources and are common precursors of PM2.5 and ozone pollution, which pose a serious threat to the environment and have adverse effects on human health. Catalytic degradation is one of the effective methods to solve CVOCs pollution, which has the advantages of low operating temperature, less chlorine-containing by-products and high degradation efficiency. The core of this technology is to design and develop catalyst materials with excellent stability and catalytic performance. At present, molecular sieve catalysts have attracted extensive attention because of their acidity and unique pore structure. In this paper, the current research status of catalysts supported by molecular sieve, such as noble metals, transition metal oxides and perovskites, and their activity, acidity, stability and selectivity in CVOCs catalytic reactions were summarized and analyzed, and the future development direction of CVOCs molecular sieve supported catalysts was prospected.
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