利用经验理论计算不同温度下丙酮和四氯化碳二元液体混合物中的超声波速度

Vijendra Singh, Ajay Kumar Singh, Mohan Bhushan Kalhans
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引用次数: 0

摘要

在 2 MHz 频率下,对温度为 286.15 K、289.15 K 和 293.15 K 的丙酮和四氯化碳二元液体混合物的超声波速度进行了实验评估,并将其作为摩尔浓度的函数。实验值与分析二元液体混合物超声波速度的各种理论进行了比较,如 Nomoto 理论 (NOM)、Van Dael 和 Vangeel 的理想混合关系 (IMR)、阻抗关系 (IDR)、拉奥比速度法 (Rao) 和俊杰关系 (JR)。应用卡方检验和平均百分比误差来研究这些理论对现有系统的相对适用性。从分子相互作用的角度讨论了体系的热声参数随分子分数的变化。
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Computation of Ultrasonic Speed in Binary Liquid Mixture of Acetone and Carbon tetrachloride using Empirical Theories at Different Temperatures
Experimental ultrasonic velocities of binary liquid mixture of acetone and carbon tetra chloride at temperatures 286.15 K, 289.15 K and 293.15 have been evaluatedat 2 MHz as a function of molar concentrations. The experimental values were compared with various theories for analysis of ultrasonic velocity in binary liquid mixtures such as Nomoto theory (NOM), ideal mixing relation (IMR) of Van Dael andVangeel, Impedance Relation (IDR), Rao’s Specific Velocity Method (Rao) and Junjie’s relations (JR). Chi-square test and average percentage error were applied to investigate the relative applicability of these theories to the present systems. The variation of thermo acoustical parameters of the systems with the mole fraction has been discussed in term of molecular interactions.
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