LLDPE 薄膜显影表面含有成核剂,可减少食物附着在薄膜表面造成的油渍,便于回收前冲洗

Nattapong Pinpru, Chiranicha Ninthap, Supang Sripraphot, Supharada Khaisaat
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摘要

本研究的目的是通过使用单一成核剂和混合成核剂来增强线性低密度聚乙烯(LLDPE)薄膜的表面性能,以减少薄膜表面因食物附着而产生的脂肪污渍,便于回收前的冲洗,从而降低回收前的能耗。该工艺首先制备含有成核剂和聚乙二醇(PEG)的高浓度 LLDPE 母料,然后进行吹膜和测试分析。结果表明,单一成核剂和混合成核剂都会使薄膜的表面特性发生重大改变。薄膜表面纹理的改变使脂肪污渍易于去除。此外,混合成核剂的使用使薄膜表面变得相当粗糙。它可以通过原子力显微镜(AFM)图像计算出平均粗糙度(Ra),该粗糙度非常低,仅为 4.7 纳米,而且粗糙度是一致的。接触角为 99.17 度,结晶度百分比明显高于单一成核剂。因此,薄膜表面的脂肪污渍更容易去除。另一方面,薄膜的视觉外观、形态、官能团和机械性能没有显著差异。总之,使用成核剂有助于轻松冲洗薄膜上的脂肪污渍。
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LLDPE film development surface with nucleating agents to reduce fat stains from food adherence on the film surface for easy rinsing before recycling
The purpose of this research was to enhance the surface of linear low-density polyethylene (LLDPE) film by using single and hybrid nucleating agents to reduce fat stains from food adherence on the film surface for easy rinsing before recycling, consequently reducing energy consumption before recycling. The process begins with the preparation of a high-concentration masterbatch of LLDPE with nucleating agents and polyethylene glycol (PEG), followed by blown film and test analysis. The results showed that both single and hybrid nucleating agents resulted in substantial modifications in the surface characteristics of the film. The altered surface texture of the film makes fat stains easy to remove. In addition, the use of hybrid nucleating agents resulted in considerable roughness on the film's surface. It can calculate the average roughness (Ra) from atomic force microscopy (AFM) images, which is very low at 4.7 nm, and the roughness is consistent. The contact angle was 99.17 degrees, and the percentage of crystallinity was clearly higher than that of a single nucleating agent. As a result, the fat stains on the film surface are easier to remove. The visual appearance, morphology, functional group, and mechanical properties of the films, on the other hand, were not significantly different. In summary, using a nucleating agent helped to rinse fat stains from the film easily.
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