Patrick S. Schmidt, Maximilian Piszko and Andreas P. Fröba*,
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引用次数: 0
摘要
这项研究报告了含有环己烷、正癸烷、正庚烷、甲苯、异丁基苯、1-甲基萘、甲醇、乙醇或丙酮的二元液体混合物中的菲克扩散系数 D11 和热扩散率 a。混合物在接近饱和条件的温度 T = 298、348 和 423 K 下进行动态光散射研究。除了等摩尔成分外,还研究了甲苯与甲醇、乙醇或环己烷的二元混合物,甲苯摩尔分数介于 0.1 和 0.9 之间。D11 和 a 的平均相对扩大实验不确定度 (k = 2) 分别为 5.3% 和 8.3%。对于所研究的体系,讨论了分子特性对扩散系数的影响,即扩散系数是 T 和组成的函数。虽然 D11 显然取决于混合物成分的分子结构,即烷烃链长、脂肪族或芳香环、羟基和羰基官能团,但在实验不确定性范围内,这种关系无法解决 a 的问题。对于含有极性物质甲醇、乙醇或丙酮的混合物,发现氢键对 D11 有影响。总的来说,已确定的结构-性质关系与文献中报道的类似体系的结构-性质关系一致。此外,还将目前的 D11 和 a 数据与相应的文献数据进行了比较。
Fick Diffusion Coefficients in Binary Liquid Mixtures Containing Alkanes, Aromatics, Alcohols, or Acetone by Using Dynamic Light Scattering
This work reports Fick diffusion coefficients D11 and thermal diffusivities a in binary liquid mixtures containing cyclohexane, n-decane, n-heptane, toluene, isobutylbenzene, 1-methylnaphthalene, methanol, ethanol, or acetone. The mixtures are investigated by dynamic light scattering at temperatures T = 298, 348, and 423 K close to saturation conditions. Besides equimolar composition, toluene-based binary mixtures with methanol, ethanol, or cyclohexane are investigated at toluene mole fractions between 0.1 and 0.9. The average relative expanded experimental uncertainties (k = 2) for D11 and a are 5.3 and 8.3%. For the studied systems, the influence of molecular characteristics on the diffusivities as a function of T and composition is discussed. While D11 clearly depends on the molecular structure of the mixture components, i.e., alkane chain length, aliphatic or aromatic rings, or hydroxyl and carbonyl functional groups, such relationships were not resolvable for a within the experimental uncertainties. For mixtures containing the polar species methanol, ethanol, or acetone, an influence of hydrogen bonding on D11 was found. In general, the identified structure–property relationships agree with those reported in the literature for similar systems. Furthermore, a comparison of the present D11 and a data with corresponding literature data is performed.
期刊介绍:
The Journal of Chemical & Engineering Data is a monthly journal devoted to the publication of data obtained from both experiment and computation, which are viewed as complementary. It is the only American Chemical Society journal primarily concerned with articles containing data on the phase behavior and the physical, thermodynamic, and transport properties of well-defined materials, including complex mixtures of known compositions. While environmental and biological samples are of interest, their compositions must be known and reproducible. As a result, adsorption on natural product materials does not generally fit within the scope of Journal of Chemical & Engineering Data.